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Mild complexation protocol for chiral Cp(x)Rh and Ir complexes suitable for in situ catalysis
A practical complexation method for chiral cyclopentadienyl (Cp(x)) iridium and rhodium complexes is described. The procedure uses the free Cp(x)H with stable and commercially available rhodium(i) and iridium(i) salts without base or additive. The conditions are mild and do not require the exclusion...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6346397/ https://www.ncbi.nlm.nih.gov/pubmed/30774871 http://dx.doi.org/10.1039/c8sc04385j |