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Hot-electron effects during reactive scattering of H(2) from Ag(111): the interplay between mode-specific electronic friction and the potential energy landscape

The breakdown of the Born–Oppenheimer approximation gives rise to nonadiabatic effects in gas-surface reactions at metal surfaces. However, for a given reaction, it remains unclear which factors quantitatively determine whether these effects measurably contribute to surface reactivity in catalysis a...

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Detalles Bibliográficos
Autores principales: Zhang, Yaolong, Maurer, Reinhard J., Guo, Hua, Jiang, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6346630/
https://www.ncbi.nlm.nih.gov/pubmed/30774906
http://dx.doi.org/10.1039/c8sc03955k