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Hot-electron effects during reactive scattering of H(2) from Ag(111): the interplay between mode-specific electronic friction and the potential energy landscape
The breakdown of the Born–Oppenheimer approximation gives rise to nonadiabatic effects in gas-surface reactions at metal surfaces. However, for a given reaction, it remains unclear which factors quantitatively determine whether these effects measurably contribute to surface reactivity in catalysis a...
Autores principales: | Zhang, Yaolong, Maurer, Reinhard J., Guo, Hua, Jiang, Bin |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6346630/ https://www.ncbi.nlm.nih.gov/pubmed/30774906 http://dx.doi.org/10.1039/c8sc03955k |
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