A low-valent dinuclear ruthenium diazadiene complex catalyzes the oxidation of dihydrogen and reversible hydrogenation of quinones

The dinuclear ruthenium complex [Ru(2)H(μ-H)(Me(2)dad)(dbcot)(2)] contains a 1,4-dimethyl-diazabuta-1,3-diene (Me(2)dad) as a non-innocent bridging ligand between the metal centers to give a [Ru(2)(Me(2)dad)] core. In addition, each ruthenium is bound to one dibenzo[a,e]cyclooctatetraene (dbcot) lig...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Xiuxiu, Gianetti, Thomas L., Wörle, Michael D., van Leest, Nicolaas P., de Bruin, Bas, Grützmacher, Hansjörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6346631/
https://www.ncbi.nlm.nih.gov/pubmed/30774909
http://dx.doi.org/10.1039/c8sc02864h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6346631/
https://www.ncbi.nlm.nih.gov/pubmed/30774909
http://dx.doi.org/10.1039/c8sc02864h

Ejemplares similares