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A low-valent dinuclear ruthenium diazadiene complex catalyzes the oxidation of dihydrogen and reversible hydrogenation of quinones
The dinuclear ruthenium complex [Ru(2)H(μ-H)(Me(2)dad)(dbcot)(2)] contains a 1,4-dimethyl-diazabuta-1,3-diene (Me(2)dad) as a non-innocent bridging ligand between the metal centers to give a [Ru(2)(Me(2)dad)] core. In addition, each ruthenium is bound to one dibenzo[a,e]cyclooctatetraene (dbcot) lig...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6346631/ https://www.ncbi.nlm.nih.gov/pubmed/30774909 http://dx.doi.org/10.1039/c8sc02864h |