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A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis
Here we report that the tri-1-adamantylphosphine-nickel complex [Ad(3)PNiBr(3)](-)[Ad(3)PH](+) upon activation with an alkylaluminoxane catalyzes the polymerization of ethylene to ultrahigh-molecular-weight, nearly linear polyethylene (M(n) up to 1.68 × 10(6) g mol(−1)) with initial activities reach...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6347634/ https://www.ncbi.nlm.nih.gov/pubmed/30683873 http://dx.doi.org/10.1038/s41467-019-08309-8 |