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Ultrasonic Exfoliation of Hydrophobic and Hydrophilic Metal–Organic Frameworks To Form Nanosheets

The modular structure of metal–organic framework nanosheets (MONs) provides a convenient route to creating two‐dimensional materials with readily tuneable surface properties. Here, the liquid exfoliation of two closely related layered metal–organic frameworks functionalised with either methoxy‐propy...

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Detalles Bibliográficos
Autores principales: Ashworth, David J., Cooper, Adam, Trueman, Mollie, Al‐Saedi, Rasha W. M., Smith, Liam D., Meijer, Anthony J. H. M., Foster, Jonathan A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6348380/
https://www.ncbi.nlm.nih.gov/pubmed/30222223
http://dx.doi.org/10.1002/chem.201803221
Descripción
Sumario:The modular structure of metal–organic framework nanosheets (MONs) provides a convenient route to creating two‐dimensional materials with readily tuneable surface properties. Here, the liquid exfoliation of two closely related layered metal–organic frameworks functionalised with either methoxy‐propyl (1) or pentyl (2) pendent groups intended to bestow either hydrophilic or hydrophobic character to the resulting nanosheets is reported. Exfoliation of the two materials in a range of different solvents highlighted significant differences in their dispersion properties, as well as their molecular and nanoscopic structures. Exchange or loss of solvent was found to occur at the labile axial position of the paddle‐wheel based MONs and DFT calculations indicated that intramolecular coordination by the oxygen of the methoxy‐propyl pendant groups may take place. The nanoscopic dimensions of the MONs were further tuned by varying the exfoliation conditions and through “liquid cascade centrifugation”. Aqueous suspensions of the nanosheets were used as sensors to detect aromatic heterocycles with clear differences in binding behaviour observed and quantified.