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δ C–H (hetero)arylation via Cu-catalyzed radical relay

A Cu-catalyzed strategy has been developed that harnesses a radical relay mechanism to intercept a distal C-centered radical for C–C bond formation. This approach enables selective δ C–H (hetero)arylation of sulfonamides via intramolecular hydrogen atom transfer (HAT) by an N-centered radical. The r...

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Detalles Bibliográficos
Autores principales:	Zhang, Zuxiao, Stateman, Leah M., Nagib, David A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6349054/ https://www.ncbi.nlm.nih.gov/pubmed/30774920 http://dx.doi.org/10.1039/c8sc04366c

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