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Catalysis of linear alkene metathesis by Grubbs-type ruthenium alkylidene complexes containing hemilabile α,α-diphenyl-(monosubstituted-pyridin-2-yl)methanolato ligands

Four new Grubbs-type precatalysts [RuCl(H(2)IMes)(O^N)(=CHPh)], where [O^N = α,α-diphenyl-(3-methylpyridin-2-yl)methanolato, α,α-diphenyl-(4-methylpyridin-2-yl)methanolato, α,α-diphenyl-(5-methylpyridin-2-yl)methanolato and α,α-diphenyl-(3-methoxypyridin-2-yl)methanolato] were synthesized and tested...

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Detalles Bibliográficos
Autores principales: Tole, Tegene T, Jordaan, Johan H L, Vosloo, Hermanus C M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6350883/
https://www.ncbi.nlm.nih.gov/pubmed/30745994
http://dx.doi.org/10.3762/bjoc.15.19