Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation

The influence of microwave and ultrasonic irradiation on the performance of ammonium-tagged Ru-based catalysts in olefin metathesis transformations in aqueous media was studied. Differences in the catalytic activity in correlation with the nature of the present counter ion and the size of the N-hete...

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Autores principales: Gułajski, Łukasz, Tracz, Andrzej, Urbaniak, Katarzyna, Czarnocki, Stefan J, Bieniek, Michał, Olszewski, Tomasz K
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6350890/
https://www.ncbi.nlm.nih.gov/pubmed/30745991
http://dx.doi.org/10.3762/bjoc.15.16
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author Gułajski, Łukasz
Tracz, Andrzej
Urbaniak, Katarzyna
Czarnocki, Stefan J
Bieniek, Michał
Olszewski, Tomasz K
author_facet Gułajski, Łukasz
Tracz, Andrzej
Urbaniak, Katarzyna
Czarnocki, Stefan J
Bieniek, Michał
Olszewski, Tomasz K
author_sort Gułajski, Łukasz
collection PubMed
description The influence of microwave and ultrasonic irradiation on the performance of ammonium-tagged Ru-based catalysts in olefin metathesis transformations in aqueous media was studied. Differences in the catalytic activity in correlation with the nature of the present counter ion and the size of the N-heterocyclic carbene (NHC) ligand were revealed. The presented methodology allows for preparation of a variety of polar and non-polar metathesis products under environmentally friendly conditions.
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spelling pubmed-63508902019-02-11 Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation Gułajski, Łukasz Tracz, Andrzej Urbaniak, Katarzyna Czarnocki, Stefan J Bieniek, Michał Olszewski, Tomasz K Beilstein J Org Chem Full Research Paper The influence of microwave and ultrasonic irradiation on the performance of ammonium-tagged Ru-based catalysts in olefin metathesis transformations in aqueous media was studied. Differences in the catalytic activity in correlation with the nature of the present counter ion and the size of the N-heterocyclic carbene (NHC) ligand were revealed. The presented methodology allows for preparation of a variety of polar and non-polar metathesis products under environmentally friendly conditions. Beilstein-Institut 2019-01-17 /pmc/articles/PMC6350890/ /pubmed/30745991 http://dx.doi.org/10.3762/bjoc.15.16 Text en Copyright © 2019, Gułajski et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Gułajski, Łukasz
Tracz, Andrzej
Urbaniak, Katarzyna
Czarnocki, Stefan J
Bieniek, Michał
Olszewski, Tomasz K
Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation
title Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation
title_full Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation
title_fullStr Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation
title_full_unstemmed Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation
title_short Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation
title_sort ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6350890/
https://www.ncbi.nlm.nih.gov/pubmed/30745991
http://dx.doi.org/10.3762/bjoc.15.16
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