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Reversible homolytic activation of water via metal–ligand cooperativity in a T-shaped Ni(ii) complex
A T-shaped Ni(ii) complex [(Tol,Ph)DHPy]Ni has been prepared and characterized. EPR spectra and DFT calculations of this complex suggest that the electronic structure is best described as a high-spin Ni(ii) center antiferromagnetically coupled with a ligand-based radical. This complex reacts with wa...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6354739/ https://www.ncbi.nlm.nih.gov/pubmed/30809351 http://dx.doi.org/10.1039/c8sc03719a |