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Reductive α-borylation of α,β-unsaturated esters using NHC–BH(3) activated by I(2) as a metal-free route to α-boryl esters
Useful α-boryl esters can be synthesized in one step from α,β-unsaturated esters using just a simple to access NHC–BH(3) (NHC = N-heterocyclic carbene) and catalytic I(2). The scope of this reductive α-borylation methodology is excellent and includes a range of alkyl, aryl substituted and cyclic and...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6354834/ https://www.ncbi.nlm.nih.gov/pubmed/30809360 http://dx.doi.org/10.1039/c8sc04305a |