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Sodium-coupled electron transfer reactivity of metal–organic frameworks containing titanium clusters: the importance of cations in redox chemistry
Stoichiometric reduction reactions of two metal–organic frameworks (MOFs) by the solution reagents [Image: see text] (M = Cr, Co) are described. The two MOFs contain clusters with Ti(8)O(8) rings: Ti(8)O(8)(OH)(4)(bdc)(6); bdc = terephthalate (MIL-125) and Ti(8)O(8)(OH)(4)(bdc-NH(2))(6); bdc-NH(2) =...
Autores principales: | Saouma, Caroline T., Tsou, Chih-Chin, Richard, Sarah, Ameloot, Rob, Vermoortele, Frederik, Smolders, Simon, Bueken, Bart, DiPasquale, Antonio G., Kaminsky, Werner, Valdez, Carolyn N., De Vos, Dirk E., Mayer, James M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6354900/ https://www.ncbi.nlm.nih.gov/pubmed/30809347 http://dx.doi.org/10.1039/c8sc04138e |
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