Designing Self‐Assembled Rosettes: Why Ammeline is a Superior Building Block to Melamine

Mostrar otras versiones (1)

Invited for this month's cover picture are Professor Célia Fonseca Guerra from Vrije Universiteit Amsterdam and Leiden University (The Netherlands) and André Nicolai Petelski from UTN‐FRRe University of Argentine (Argentina). The cover picture shows a colored pallet of melamine and ammeline tau...

Descripción completa

Detalles Bibliográficos
Autores principales: Petelski, André Nicolai, Fonseca Guerra, Célia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Cover Profile
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6356162/
https://www.ncbi.nlm.nih.gov/pubmed/30740287
http://dx.doi.org/10.1002/open.201900001
_version_ 1783391464981528576
author Petelski, André Nicolai
Fonseca Guerra, Célia
author_facet Petelski, André Nicolai
Fonseca Guerra, Célia
author_sort Petelski, André Nicolai
collection PubMed
description Invited for this month's cover picture are Professor Célia Fonseca Guerra from Vrije Universiteit Amsterdam and Leiden University (The Netherlands) and André Nicolai Petelski from UTN‐FRRe University of Argentine (Argentina). The cover picture shows a colored pallet of melamine and ammeline tautomers that form hydrogen‐bonded hexameric rosettes. When it comes to self‐assembling capabilities, one of the ammeline structures (red) is shown to be distinctly superior to melamine, both in the gas phase and in water. Quantum chemical computations explain that this is due to the presence of stronger pair interactions and the manifestation of a large cooperativity effect. Read the full text of their Full Paper at 10.1002/open.201800210.
format Online
Article
Text
id pubmed-6356162
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-63561622019-02-08 Designing Self‐Assembled Rosettes: Why Ammeline is a Superior Building Block to Melamine Petelski, André Nicolai Fonseca Guerra, Célia ChemistryOpen Cover Profile Invited for this month's cover picture are Professor Célia Fonseca Guerra from Vrije Universiteit Amsterdam and Leiden University (The Netherlands) and André Nicolai Petelski from UTN‐FRRe University of Argentine (Argentina). The cover picture shows a colored pallet of melamine and ammeline tautomers that form hydrogen‐bonded hexameric rosettes. When it comes to self‐assembling capabilities, one of the ammeline structures (red) is shown to be distinctly superior to melamine, both in the gas phase and in water. Quantum chemical computations explain that this is due to the presence of stronger pair interactions and the manifestation of a large cooperativity effect. Read the full text of their Full Paper at 10.1002/open.201800210. John Wiley and Sons Inc. 2019-01-14 /pmc/articles/PMC6356162/ /pubmed/30740287 http://dx.doi.org/10.1002/open.201900001 Text en © 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
spellingShingle Cover Profile
Petelski, André Nicolai
Fonseca Guerra, Célia
Designing Self‐Assembled Rosettes: Why Ammeline is a Superior Building Block to Melamine
title Designing Self‐Assembled Rosettes: Why Ammeline is a Superior Building Block to Melamine
title_full Designing Self‐Assembled Rosettes: Why Ammeline is a Superior Building Block to Melamine
title_fullStr Designing Self‐Assembled Rosettes: Why Ammeline is a Superior Building Block to Melamine
title_full_unstemmed Designing Self‐Assembled Rosettes: Why Ammeline is a Superior Building Block to Melamine
title_short Designing Self‐Assembled Rosettes: Why Ammeline is a Superior Building Block to Melamine
title_sort designing self‐assembled rosettes: why ammeline is a superior building block to melamine
topic Cover Profile
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6356162/
https://www.ncbi.nlm.nih.gov/pubmed/30740287
http://dx.doi.org/10.1002/open.201900001
work_keys_str_mv AT petelskiandrenicolai designingselfassembledrosetteswhyammelineisasuperiorbuildingblocktomelamine
AT fonsecaguerracelia designingselfassembledrosetteswhyammelineisasuperiorbuildingblocktomelamine

Ejemplares similares