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Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model
Half‐sandwich Rh(I) compounds display good catalytic activity toward alkyne [2+2+2] cycloadditions. A peculiar structural feature of these catalysts is the coordination of the metal to an aromatic moiety, typically a cyclopentadienyl anion, and, in particular, the possibility to change the bonding m...
Autores principales: | Dalla Tiezza, Marco, Bickelhaupt, F. Matthias, Orian, Laura |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6356173/ https://www.ncbi.nlm.nih.gov/pubmed/30740289 http://dx.doi.org/10.1002/open.201800191 |
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