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Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model

Half‐sandwich Rh(I) compounds display good catalytic activity toward alkyne [2+2+2] cycloadditions. A peculiar structural feature of these catalysts is the coordination of the metal to an aromatic moiety, typically a cyclopentadienyl anion, and, in particular, the possibility to change the bonding m...

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Detalles Bibliográficos
Autores principales: Dalla Tiezza, Marco, Bickelhaupt, F. Matthias, Orian, Laura
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6356173/
https://www.ncbi.nlm.nih.gov/pubmed/30740289
http://dx.doi.org/10.1002/open.201800191

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