Cargando…

Cover Feature: Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model (ChemistryOpen 2/2019)

The Cover Feature shows the glacier of Marmolada, the highest Dolomite (3343 m), with superimposed the aromatic ligand of the group 9 half‐matallocene catalysts for [2+2+2] cycloadditions of unsaturated molecules. When large changes of metal slippage from the centroid of the coordinated cyclopentadi...

Descripción completa

Detalles Bibliográficos
Autores principales: Dalla Tiezza, Marco, Bickelhaupt, F. Matthias, Orian, Laura
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6356179/
http://dx.doi.org/10.1002/open.201900003
_version_ 1783391469720043520
author Dalla Tiezza, Marco
Bickelhaupt, F. Matthias
Orian, Laura
author_facet Dalla Tiezza, Marco
Bickelhaupt, F. Matthias
Orian, Laura
author_sort Dalla Tiezza, Marco
collection PubMed
description The Cover Feature shows the glacier of Marmolada, the highest Dolomite (3343 m), with superimposed the aromatic ligand of the group 9 half‐matallocene catalysts for [2+2+2] cycloadditions of unsaturated molecules. When large changes of metal slippage from the centroid of the coordinated cyclopentadienyl moiety occur during catalysis, the turnover frequency (TOF) of the catalytic cycle decreases, similar to what happens to the inexperienced climber who drifts on ice and gets away from the longed‐for TOP. (Photo credit to Foto Riva) More information can be found in the Full Paper by M. Dalla Tiezza et al. on page 143 in Issue 2, 2019 (DOI: 10.1002/open.201800191).[Image: see text]
format Online
Article
Text
id pubmed-6356179
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-63561792019-02-08 Cover Feature: Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model (ChemistryOpen 2/2019) Dalla Tiezza, Marco Bickelhaupt, F. Matthias Orian, Laura ChemistryOpen Cover Pictures The Cover Feature shows the glacier of Marmolada, the highest Dolomite (3343 m), with superimposed the aromatic ligand of the group 9 half‐matallocene catalysts for [2+2+2] cycloadditions of unsaturated molecules. When large changes of metal slippage from the centroid of the coordinated cyclopentadienyl moiety occur during catalysis, the turnover frequency (TOF) of the catalytic cycle decreases, similar to what happens to the inexperienced climber who drifts on ice and gets away from the longed‐for TOP. (Photo credit to Foto Riva) More information can be found in the Full Paper by M. Dalla Tiezza et al. on page 143 in Issue 2, 2019 (DOI: 10.1002/open.201800191).[Image: see text] John Wiley and Sons Inc. 2019-01-14 /pmc/articles/PMC6356179/ http://dx.doi.org/10.1002/open.201900003 Text en © 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
spellingShingle Cover Pictures
Dalla Tiezza, Marco
Bickelhaupt, F. Matthias
Orian, Laura
Cover Feature: Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model (ChemistryOpen 2/2019)
title Cover Feature: Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model (ChemistryOpen 2/2019)
title_full Cover Feature: Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model (ChemistryOpen 2/2019)
title_fullStr Cover Feature: Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model (ChemistryOpen 2/2019)
title_full_unstemmed Cover Feature: Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model (ChemistryOpen 2/2019)
title_short Cover Feature: Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model (ChemistryOpen 2/2019)
title_sort cover feature: half‐sandwich metal‐catalyzed alkyne [2+2+2] cycloadditions and the slippage span model (chemistryopen 2/2019)
topic Cover Pictures
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6356179/
http://dx.doi.org/10.1002/open.201900003
work_keys_str_mv AT dallatiezzamarco coverfeaturehalfsandwichmetalcatalyzedalkyne222cycloadditionsandtheslippagespanmodelchemistryopen22019
AT bickelhauptfmatthias coverfeaturehalfsandwichmetalcatalyzedalkyne222cycloadditionsandtheslippagespanmodelchemistryopen22019
AT orianlaura coverfeaturehalfsandwichmetalcatalyzedalkyne222cycloadditionsandtheslippagespanmodelchemistryopen22019