Cargando…
Synergistic Effect on the Thermomechanical and Electrical Properties of Epoxy Composites with the Enhancement of Carbon Nanotubes and Graphene Nano Platelets
The synergetic effect of adding multi-walled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) on the thermomechanical properties and electric resistance of epoxy polymers were experimentally analyzed in this study. The total content of two employed carbon fillers were kept constant at 0.4...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6357122/ https://www.ncbi.nlm.nih.gov/pubmed/30646568 http://dx.doi.org/10.3390/ma12020255 |
_version_ | 1783391723593924608 |
---|---|
author | Jen, Yi-Ming Huang, Jui-Cheng |
author_facet | Jen, Yi-Ming Huang, Jui-Cheng |
author_sort | Jen, Yi-Ming |
collection | PubMed |
description | The synergetic effect of adding multi-walled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) on the thermomechanical properties and electric resistance of epoxy polymers were experimentally analyzed in this study. The total content of two employed carbon fillers were kept constant at 0.4 wt %, and seven filler ratios between two fillers (MWCNTs:GNPs), i.e., 10:0, 1:9, 3:7, 5:5, 7:3, 9:1, and 0:10, were considered in the experimental program to investigate the influences of employed nano-filler ratios on the viscoelastic and electrical properties of the studied nanocomposites. The thermomechanical properties and the sheet resistance of the nanocomposites were analyzed using a dynamic mechanical analyzer and four-point probe, respectively. Moreover, the thermogravimetric analyzer was utilized to measure the pyrolysis temperature of the nanocomposites. Experimental results show that the synergistic effect of adding two nano-fillers were clear for the improvement of the storage moduli, glass transition temperatures, and electric conductivity. Oppositely, the employment of two fillers has a slight effect on the pyrolysis temperatures of the studied nanocomposites. The composites with the MWCNT:GNP ratio of 1:9 display the most apparent enhancement of the thermomechanical properties. The improvement results from the uniform distribution and the high aspect ratio of GNPs. The addition of a small amount of MWCNTs provides more linkage in the matrix. Moreover, the specimens with the MWCNT:GNP ratio of 1:9 shows remarkable electrical properties, which result from the large contact surface areas of GNPs with each other. The employment of few MWCNTs plays an important bridging role between the layered GNPs. |
format | Online Article Text |
id | pubmed-6357122 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-63571222019-02-04 Synergistic Effect on the Thermomechanical and Electrical Properties of Epoxy Composites with the Enhancement of Carbon Nanotubes and Graphene Nano Platelets Jen, Yi-Ming Huang, Jui-Cheng Materials (Basel) Article The synergetic effect of adding multi-walled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) on the thermomechanical properties and electric resistance of epoxy polymers were experimentally analyzed in this study. The total content of two employed carbon fillers were kept constant at 0.4 wt %, and seven filler ratios between two fillers (MWCNTs:GNPs), i.e., 10:0, 1:9, 3:7, 5:5, 7:3, 9:1, and 0:10, were considered in the experimental program to investigate the influences of employed nano-filler ratios on the viscoelastic and electrical properties of the studied nanocomposites. The thermomechanical properties and the sheet resistance of the nanocomposites were analyzed using a dynamic mechanical analyzer and four-point probe, respectively. Moreover, the thermogravimetric analyzer was utilized to measure the pyrolysis temperature of the nanocomposites. Experimental results show that the synergistic effect of adding two nano-fillers were clear for the improvement of the storage moduli, glass transition temperatures, and electric conductivity. Oppositely, the employment of two fillers has a slight effect on the pyrolysis temperatures of the studied nanocomposites. The composites with the MWCNT:GNP ratio of 1:9 display the most apparent enhancement of the thermomechanical properties. The improvement results from the uniform distribution and the high aspect ratio of GNPs. The addition of a small amount of MWCNTs provides more linkage in the matrix. Moreover, the specimens with the MWCNT:GNP ratio of 1:9 shows remarkable electrical properties, which result from the large contact surface areas of GNPs with each other. The employment of few MWCNTs plays an important bridging role between the layered GNPs. MDPI 2019-01-14 /pmc/articles/PMC6357122/ /pubmed/30646568 http://dx.doi.org/10.3390/ma12020255 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Jen, Yi-Ming Huang, Jui-Cheng Synergistic Effect on the Thermomechanical and Electrical Properties of Epoxy Composites with the Enhancement of Carbon Nanotubes and Graphene Nano Platelets |
title | Synergistic Effect on the Thermomechanical and Electrical Properties of Epoxy Composites with the Enhancement of Carbon Nanotubes and Graphene Nano Platelets |
title_full | Synergistic Effect on the Thermomechanical and Electrical Properties of Epoxy Composites with the Enhancement of Carbon Nanotubes and Graphene Nano Platelets |
title_fullStr | Synergistic Effect on the Thermomechanical and Electrical Properties of Epoxy Composites with the Enhancement of Carbon Nanotubes and Graphene Nano Platelets |
title_full_unstemmed | Synergistic Effect on the Thermomechanical and Electrical Properties of Epoxy Composites with the Enhancement of Carbon Nanotubes and Graphene Nano Platelets |
title_short | Synergistic Effect on the Thermomechanical and Electrical Properties of Epoxy Composites with the Enhancement of Carbon Nanotubes and Graphene Nano Platelets |
title_sort | synergistic effect on the thermomechanical and electrical properties of epoxy composites with the enhancement of carbon nanotubes and graphene nano platelets |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6357122/ https://www.ncbi.nlm.nih.gov/pubmed/30646568 http://dx.doi.org/10.3390/ma12020255 |
work_keys_str_mv | AT jenyiming synergisticeffectonthethermomechanicalandelectricalpropertiesofepoxycompositeswiththeenhancementofcarbonnanotubesandgraphenenanoplatelets AT huangjuicheng synergisticeffectonthethermomechanicalandelectricalpropertiesofepoxycompositeswiththeenhancementofcarbonnanotubesandgraphenenanoplatelets |