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Crystal structure of (2-acetylferrocen-1-yl)boronic acid
(2-Acetylferrocen-1-yl)boronic acid, [Fe(C(5)H(5))(C(7)H(8)BO(3))] or 2-C(O)CH(3)-1-B(OH)(2)–Fc [Fc = Fe(η(5)-C(5)H(3))(η(5)-C(5)H(5))], crystallizes in the centrosymmetric space group P2(1)/n. The boronic acid functionality interacts via intramolecular hydrogen bonds with the acetyl group and wi...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6362635/ https://www.ncbi.nlm.nih.gov/pubmed/30800465 http://dx.doi.org/10.1107/S2056989019001178 |
Sumario: | (2-Acetylferrocen-1-yl)boronic acid, [Fe(C(5)H(5))(C(7)H(8)BO(3))] or 2-C(O)CH(3)-1-B(OH)(2)–Fc [Fc = Fe(η(5)-C(5)H(3))(η(5)-C(5)H(5))], crystallizes in the centrosymmetric space group P2(1)/n. The boronic acid functionality interacts via intramolecular hydrogen bonds with the acetyl group and with the –B(OH)(2) functionality of an adjacent molecule. The resulting centrosymmetric dimer exhibits an anti-positioning of the ferrocenyl moieties towards the central B(2)O(4) plane. Consequently, an (R(p),S(p))-, i.e. a meso configuration is present for this dimer. In the crystal, weak C—H⋯O hydrogen bonds consolidate the molecular packing. |
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