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Crystal structure of 2-[(2E)-2-methyl-3-phenyl­prop-2-en-1-yl­idene]-N-phenyl­hydrazinecarboxamide

The title compound, C(17)H(17)N(3)O, crystallizes with two independent mol­ecules in the asymmetric unit. The semicarbazone moieties of these independent mol­ecules (I and II) are essentially planar [maximum deviation of 0.042 (1) Å in mol­ecule I and 0.041 (1) Å in mol­ecule II], with the terminal...

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Autores principales: Saritha, S. R., Anitha, L., Layana, S. R., Sithambaresan, M., Sudarsanakumar, M. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6362643/
https://www.ncbi.nlm.nih.gov/pubmed/30800444
http://dx.doi.org/10.1107/S2056989018018376
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author Saritha, S. R.
Anitha, L.
Layana, S. R.
Sithambaresan, M.
Sudarsanakumar, M. R.
author_facet Saritha, S. R.
Anitha, L.
Layana, S. R.
Sithambaresan, M.
Sudarsanakumar, M. R.
author_sort Saritha, S. R.
collection PubMed
description The title compound, C(17)H(17)N(3)O, crystallizes with two independent mol­ecules in the asymmetric unit. The semicarbazone moieties of these independent mol­ecules (I and II) are essentially planar [maximum deviation of 0.042 (1) Å in mol­ecule I and 0.041 (1) Å in mol­ecule II], with the terminal phenyl rings twisted away from the mean plane of the semicarbazone moiety, making dihedral angles of 60.26 (8) and 28.76 (9)° in mol­ecule I and 31.07 (9) and 35.45 (8)° in mol­ecule II. The mol­ecules both exhibit an E configuration with respect to the C=C and azomethine C=N bonds. In the crystal, two classical N—H⋯O hydrogen-bonding inter­actions are present between the two mol­ecules, forming a centrosymmetric dimer, while a weak C—H⋯O non-classical hydrogen-bonding inter­action, with a donor–acceptor distance of 3.476 (2) Å, inter­connects two neighbouring centrosymmetric dimers to form a cage-like structure. These cage structures are inter­connected by weak C—H⋯π inter­actions with an H⋯π distance of 2.790 Å, forming supra­molecular chains along the c-axis direction.
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spelling pubmed-63626432019-02-22 Crystal structure of 2-[(2E)-2-methyl-3-phenyl­prop-2-en-1-yl­idene]-N-phenyl­hydrazinecarboxamide Saritha, S. R. Anitha, L. Layana, S. R. Sithambaresan, M. Sudarsanakumar, M. R. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(17)H(17)N(3)O, crystallizes with two independent mol­ecules in the asymmetric unit. The semicarbazone moieties of these independent mol­ecules (I and II) are essentially planar [maximum deviation of 0.042 (1) Å in mol­ecule I and 0.041 (1) Å in mol­ecule II], with the terminal phenyl rings twisted away from the mean plane of the semicarbazone moiety, making dihedral angles of 60.26 (8) and 28.76 (9)° in mol­ecule I and 31.07 (9) and 35.45 (8)° in mol­ecule II. The mol­ecules both exhibit an E configuration with respect to the C=C and azomethine C=N bonds. In the crystal, two classical N—H⋯O hydrogen-bonding inter­actions are present between the two mol­ecules, forming a centrosymmetric dimer, while a weak C—H⋯O non-classical hydrogen-bonding inter­action, with a donor–acceptor distance of 3.476 (2) Å, inter­connects two neighbouring centrosymmetric dimers to form a cage-like structure. These cage structures are inter­connected by weak C—H⋯π inter­actions with an H⋯π distance of 2.790 Å, forming supra­molecular chains along the c-axis direction. International Union of Crystallography 2019-01-08 /pmc/articles/PMC6362643/ /pubmed/30800444 http://dx.doi.org/10.1107/S2056989018018376 Text en © Saritha et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Saritha, S. R.
Anitha, L.
Layana, S. R.
Sithambaresan, M.
Sudarsanakumar, M. R.
Crystal structure of 2-[(2E)-2-methyl-3-phenyl­prop-2-en-1-yl­idene]-N-phenyl­hydrazinecarboxamide
title Crystal structure of 2-[(2E)-2-methyl-3-phenyl­prop-2-en-1-yl­idene]-N-phenyl­hydrazinecarboxamide
title_full Crystal structure of 2-[(2E)-2-methyl-3-phenyl­prop-2-en-1-yl­idene]-N-phenyl­hydrazinecarboxamide
title_fullStr Crystal structure of 2-[(2E)-2-methyl-3-phenyl­prop-2-en-1-yl­idene]-N-phenyl­hydrazinecarboxamide
title_full_unstemmed Crystal structure of 2-[(2E)-2-methyl-3-phenyl­prop-2-en-1-yl­idene]-N-phenyl­hydrazinecarboxamide
title_short Crystal structure of 2-[(2E)-2-methyl-3-phenyl­prop-2-en-1-yl­idene]-N-phenyl­hydrazinecarboxamide
title_sort crystal structure of 2-[(2e)-2-methyl-3-phenyl­prop-2-en-1-yl­idene]-n-phenyl­hydrazinecarboxamide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6362643/
https://www.ncbi.nlm.nih.gov/pubmed/30800444
http://dx.doi.org/10.1107/S2056989018018376
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