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Crystal structure of a new 2,6-bis(imino)pyridine derivative: (1E,1′E)-1,1′-(pyridine-2,6-diyl)bis[N-(4-chlorophenyl)ethan-1-imine]
The asymmetric unit of the title compound, C(21)H(17)Cl(2)N(3), contains two crystallographically independent molecules (A and B). Both molecules have E configurations for both imine double bonds with regard to the aryl and pyridine groups. The conformations of the two molecules differ with the 4...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6362651/ https://www.ncbi.nlm.nih.gov/pubmed/30800433 http://dx.doi.org/10.1107/S2056989018017966 |
Sumario: | The asymmetric unit of the title compound, C(21)H(17)Cl(2)N(3), contains two crystallographically independent molecules (A and B). Both molecules have E configurations for both imine double bonds with regard to the aryl and pyridine groups. The conformations of the two molecules differ with the 4-chlorophenyl rings being inclined to the central pyridine ring by 77.64 (6) and 86.18 (6)° in molecule A, and 80.02 (5) and 43.41 (6)° in molecule B. In the crystal, molecules are linked by a number of C—H⋯π interactions, forming layers parallel to the bc plane. |
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