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Crystal structure of tris(2,2′-bipyridine)cobalt(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide)
In the title compound, [Co(C(10)H(8)N(2))(3)](C(9)H(5)N(4)O)(2), the tris(2,2′-bipyridine)cobalt(II) dication lies across a twofold rotation axes in the space group C2/c. The N atoms of the three bipyridine ligands form a distorted octahedron around the cobalt ion. All the N atoms of the polyni...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6362655/ https://www.ncbi.nlm.nih.gov/pubmed/30800439 http://dx.doi.org/10.1107/S2056989018018261 |
| _version_ | 1783392964308893696 |
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| author | Benabdallah, Jamila Setifi, Zouaoui Setifi, Fatima Boughzala, Habib Titi, Abderrahim |
| author_facet | Benabdallah, Jamila Setifi, Zouaoui Setifi, Fatima Boughzala, Habib Titi, Abderrahim |
| author_sort | Benabdallah, Jamila |
| collection | PubMed |
| description | In the title compound, [Co(C(10)H(8)N(2))(3)](C(9)H(5)N(4)O)(2), the tris(2,2′-bipyridine)cobalt(II) dication lies across a twofold rotation axes in the space group C2/c. The N atoms of the three bipyridine ligands form a distorted octahedron around the cobalt ion. All the N atoms of the polynitrile 1,1,3,3-tetracyano-2-ethoxypropenide anions participate in C—H⋯N hydrogen bonds ensuring crystal cohesion and forming a three-dimensional structure. The structure is further stabilized by C—H⋯π(cation) and anion⋯π(cation) interactions. |
| format | Online Article Text |
| id | pubmed-6362655 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2019 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-63626552019-02-22 Crystal structure of tris(2,2′-bipyridine)cobalt(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) Benabdallah, Jamila Setifi, Zouaoui Setifi, Fatima Boughzala, Habib Titi, Abderrahim Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Co(C(10)H(8)N(2))(3)](C(9)H(5)N(4)O)(2), the tris(2,2′-bipyridine)cobalt(II) dication lies across a twofold rotation axes in the space group C2/c. The N atoms of the three bipyridine ligands form a distorted octahedron around the cobalt ion. All the N atoms of the polynitrile 1,1,3,3-tetracyano-2-ethoxypropenide anions participate in C—H⋯N hydrogen bonds ensuring crystal cohesion and forming a three-dimensional structure. The structure is further stabilized by C—H⋯π(cation) and anion⋯π(cation) interactions. International Union of Crystallography 2019-01-04 /pmc/articles/PMC6362655/ /pubmed/30800439 http://dx.doi.org/10.1107/S2056989018018261 Text en © Benabdallah et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
| spellingShingle | Research Communications Benabdallah, Jamila Setifi, Zouaoui Setifi, Fatima Boughzala, Habib Titi, Abderrahim Crystal structure of tris(2,2′-bipyridine)cobalt(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
| title | Crystal structure of tris(2,2′-bipyridine)cobalt(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
| title_full | Crystal structure of tris(2,2′-bipyridine)cobalt(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
| title_fullStr | Crystal structure of tris(2,2′-bipyridine)cobalt(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
| title_full_unstemmed | Crystal structure of tris(2,2′-bipyridine)cobalt(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
| title_short | Crystal structure of tris(2,2′-bipyridine)cobalt(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
| title_sort | crystal structure of tris(2,2′-bipyridine)cobalt(ii) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6362655/ https://www.ncbi.nlm.nih.gov/pubmed/30800439 http://dx.doi.org/10.1107/S2056989018018261 |
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