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Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene
In the title compound, C(14)H(8)Cl(2)FN(3)O(2), the 4-fluorophenyl ring and the nitro-substituted benzene ring form a dihedral angle of 63.29 (8)°. In the crystal, molecules are linked by C—H⋯O hydrogen bonds into chains running parallel to the c axis. The crystal packing is further stabilized by...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6362658/ https://www.ncbi.nlm.nih.gov/pubmed/30800458 http://dx.doi.org/10.1107/S2056989019000707 |
| _version_ | 1783392965093228544 |
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| author | Atioğlu, Zeliha Akkurt, Mehmet Shikhaliyev, Namiq Q. Suleymanova, Gulnar T. Bagirova, Khanim N. Toze, Flavien A. A. |
| author_facet | Atioğlu, Zeliha Akkurt, Mehmet Shikhaliyev, Namiq Q. Suleymanova, Gulnar T. Bagirova, Khanim N. Toze, Flavien A. A. |
| author_sort | Atioğlu, Zeliha |
| collection | PubMed |
| description | In the title compound, C(14)H(8)Cl(2)FN(3)O(2), the 4-fluorophenyl ring and the nitro-substituted benzene ring form a dihedral angle of 63.29 (8)°. In the crystal, molecules are linked by C—H⋯O hydrogen bonds into chains running parallel to the c axis. The crystal packing is further stabilized by C—Cl⋯π, C—F⋯π and N—O⋯π interactions. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H⋯O/O⋯H (15.5%), H⋯H (15.3%), Cl⋯H/H⋯Cl (13.8%), C⋯H/H⋯C (9.5%) and F⋯H/H⋯F (8.2%) interactions. |
| format | Online Article Text |
| id | pubmed-6362658 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2019 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-63626582019-02-22 Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene Atioğlu, Zeliha Akkurt, Mehmet Shikhaliyev, Namiq Q. Suleymanova, Gulnar T. Bagirova, Khanim N. Toze, Flavien A. A. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(14)H(8)Cl(2)FN(3)O(2), the 4-fluorophenyl ring and the nitro-substituted benzene ring form a dihedral angle of 63.29 (8)°. In the crystal, molecules are linked by C—H⋯O hydrogen bonds into chains running parallel to the c axis. The crystal packing is further stabilized by C—Cl⋯π, C—F⋯π and N—O⋯π interactions. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H⋯O/O⋯H (15.5%), H⋯H (15.3%), Cl⋯H/H⋯Cl (13.8%), C⋯H/H⋯C (9.5%) and F⋯H/H⋯F (8.2%) interactions. International Union of Crystallography 2019-01-18 /pmc/articles/PMC6362658/ /pubmed/30800458 http://dx.doi.org/10.1107/S2056989019000707 Text en © Atioğlu et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
| spellingShingle | Research Communications Atioğlu, Zeliha Akkurt, Mehmet Shikhaliyev, Namiq Q. Suleymanova, Gulnar T. Bagirova, Khanim N. Toze, Flavien A. A. Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene |
| title | Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene |
| title_full | Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene |
| title_short | Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene |
| title_sort | crystal structure and hirshfeld surface analysis of (e)-1-[2,2-dichloro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6362658/ https://www.ncbi.nlm.nih.gov/pubmed/30800458 http://dx.doi.org/10.1107/S2056989019000707 |
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