Redetermination of the crystal structure of tetra­lithium octa­fluorido­zirconate(IV), Li(4)ZrF(8), from single-crystal X-ray data

Presented herein is the crystal-structure redetermination of Li(4)ZrF(8) from single-crystal X-ray data. Alkali zirconium fluorides are important in nuclear-relevant technologies, and zirconium is commonly employed as an analogue for tetra­valent f-block elements. The previous structure report of th...

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Autores principales: Chemey, Alexander T., Albrecht-Schmitt, Thomas E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6362661/
https://www.ncbi.nlm.nih.gov/pubmed/30800438
http://dx.doi.org/10.1107/S2056989018018194
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author Chemey, Alexander T.
Albrecht-Schmitt, Thomas E.
author_facet Chemey, Alexander T.
Albrecht-Schmitt, Thomas E.
author_sort Chemey, Alexander T.
collection PubMed
description Presented herein is the crystal-structure redetermination of Li(4)ZrF(8) from single-crystal X-ray data. Alkali zirconium fluorides are important in nuclear-relevant technologies, and zirconium is commonly employed as an analogue for tetra­valent f-block elements. The previous structure report of this species is based on powder X-ray data [Dugat et al. (1995 ▸). J. Solid State Chem. 120, 187–196] but there has never been a refined structure model from single-crystal data. The octa­fluorido­zirconate moieties are held together by electrostatic attraction to lithium ions without sharing of fluoride sites between zirconium(IV) ions.
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spelling pubmed-63626612019-02-22 Redetermination of the crystal structure of tetra­lithium octa­fluorido­zirconate(IV), Li(4)ZrF(8), from single-crystal X-ray data Chemey, Alexander T. Albrecht-Schmitt, Thomas E. Acta Crystallogr E Crystallogr Commun Research Communications Presented herein is the crystal-structure redetermination of Li(4)ZrF(8) from single-crystal X-ray data. Alkali zirconium fluorides are important in nuclear-relevant technologies, and zirconium is commonly employed as an analogue for tetra­valent f-block elements. The previous structure report of this species is based on powder X-ray data [Dugat et al. (1995 ▸). J. Solid State Chem. 120, 187–196] but there has never been a refined structure model from single-crystal data. The octa­fluorido­zirconate moieties are held together by electrostatic attraction to lithium ions without sharing of fluoride sites between zirconium(IV) ions. International Union of Crystallography 2019-01-04 /pmc/articles/PMC6362661/ /pubmed/30800438 http://dx.doi.org/10.1107/S2056989018018194 Text en © Chemey and Albrecht-Schmitt 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Chemey, Alexander T.
Albrecht-Schmitt, Thomas E.
Redetermination of the crystal structure of tetra­lithium octa­fluorido­zirconate(IV), Li(4)ZrF(8), from single-crystal X-ray data
title Redetermination of the crystal structure of tetra­lithium octa­fluorido­zirconate(IV), Li(4)ZrF(8), from single-crystal X-ray data
title_full Redetermination of the crystal structure of tetra­lithium octa­fluorido­zirconate(IV), Li(4)ZrF(8), from single-crystal X-ray data
title_fullStr Redetermination of the crystal structure of tetra­lithium octa­fluorido­zirconate(IV), Li(4)ZrF(8), from single-crystal X-ray data
title_full_unstemmed Redetermination of the crystal structure of tetra­lithium octa­fluorido­zirconate(IV), Li(4)ZrF(8), from single-crystal X-ray data
title_short Redetermination of the crystal structure of tetra­lithium octa­fluorido­zirconate(IV), Li(4)ZrF(8), from single-crystal X-ray data
title_sort redetermination of the crystal structure of tetra­lithium octa­fluorido­zirconate(iv), li(4)zrf(8), from single-crystal x-ray data
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6362661/
https://www.ncbi.nlm.nih.gov/pubmed/30800438
http://dx.doi.org/10.1107/S2056989018018194
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