Emergence of the structure-directing role of f-orbital overlap-driven covalency

FEUDAL (f’s essentially unaffected, d’s accommodate ligands) is a longstanding bonding model in actinide chemistry, in which metal-ligand binding uses 6d-orbitals, with the 5f remaining non-bonding. The inverse-trans-influence (ITI) is a case where the model may break down, and it has been suggested...

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Detalles Bibliográficos
Autores principales: Lu, Erli, Sajjad, Saira, Berryman, Victoria E. J., Wooles, Ashley J., Kaltsoyannis, Nikolas, Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6367379/
https://www.ncbi.nlm.nih.gov/pubmed/30733443
http://dx.doi.org/10.1038/s41467-019-08553-y

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6367379/
https://www.ncbi.nlm.nih.gov/pubmed/30733443
http://dx.doi.org/10.1038/s41467-019-08553-y

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