Synthesis of 1,2-divinylcyclopropanes by metal-catalyzed cyclopropanation of 1,3-dienes with cyclopropenes as vinyl carbene precursors

The synthesis of 1,2-divinylcyclopropanes by the reaction of cyclopropenes with 1,3-dienes is reported. The process relies on the ability of ZnCl(2) or [Rh(2)(OAc)(4)] to generate metal–vinyl carbene intermediates from cyclopropenes, which effect cyclopropanation of 1,3-dienes. Most of the reactions...

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Detalles Bibliográficos
Autores principales: González, Jesús, de la Fuente, Alba, González, María J, Díez de Tejada, Laura, López, Luis A, Vicente, Rubén
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6369990/
https://www.ncbi.nlm.nih.gov/pubmed/30800178
http://dx.doi.org/10.3762/bjoc.15.25

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