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Reusable and highly enantioselective water-soluble Ru(II)-Amm-Pheox catalyst for intramolecular cyclopropanation of diazo compounds

A reusable and highly enantioselective catalyst for the intramolecular cyclopropanation of various diazo ester and Weinreb amide derivatives was developed. The reactions catalyzed by a water-soluble Ru(II)-Amm-Pheox catalyst proceeded smoothly at room temperature, affording the corresponding bicycli...

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Detalles Bibliográficos
Autores principales: Mandour, Hamada S A, Nakagawa, Yoko, Tone, Masaya, Inoue, Hayato, Otog, Nansalmaa, Fujisawa, Ikuhide, Chanthamath, Soda, Iwasa, Seiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6369996/
https://www.ncbi.nlm.nih.gov/pubmed/30800184
http://dx.doi.org/10.3762/bjoc.15.31