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Simple electrochemical reduction of nitrones to amines

The use of electricity allows the reduction of nitrones containing aromatic and heteroaromatic rings to the corresponding amines. The main advantage of this protocol relies on the fact that only electrons are needed, avoiding the use of different chemicals and harsh procedures, something that reinfo...

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Detalles Bibliográficos
Autores principales: Rodrigo, Eduardo, Waldvogel, Siegfried R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6375361/
https://www.ncbi.nlm.nih.gov/pubmed/30842861
http://dx.doi.org/10.1039/c8sc04337j
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author Rodrigo, Eduardo
Waldvogel, Siegfried R.
author_facet Rodrigo, Eduardo
Waldvogel, Siegfried R.
author_sort Rodrigo, Eduardo
collection PubMed
description The use of electricity allows the reduction of nitrones containing aromatic and heteroaromatic rings to the corresponding amines. The main advantage of this protocol relies on the fact that only electrons are needed, avoiding the use of different chemicals and harsh procedures, something that reinforces some green aspects. The conversion tolerates different moieties and a large variety of functional groups. In addition, this electrolysis can be performed on a simple undivided beaker-type cell with constant current conditions.
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spelling pubmed-63753612019-03-06 Simple electrochemical reduction of nitrones to amines Rodrigo, Eduardo Waldvogel, Siegfried R. Chem Sci Chemistry The use of electricity allows the reduction of nitrones containing aromatic and heteroaromatic rings to the corresponding amines. The main advantage of this protocol relies on the fact that only electrons are needed, avoiding the use of different chemicals and harsh procedures, something that reinforces some green aspects. The conversion tolerates different moieties and a large variety of functional groups. In addition, this electrolysis can be performed on a simple undivided beaker-type cell with constant current conditions. Royal Society of Chemistry 2018-12-11 /pmc/articles/PMC6375361/ /pubmed/30842861 http://dx.doi.org/10.1039/c8sc04337j Text en This journal is © The Royal Society of Chemistry 2019 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Rodrigo, Eduardo
Waldvogel, Siegfried R.
Simple electrochemical reduction of nitrones to amines
title Simple electrochemical reduction of nitrones to amines
title_full Simple electrochemical reduction of nitrones to amines
title_fullStr Simple electrochemical reduction of nitrones to amines
title_full_unstemmed Simple electrochemical reduction of nitrones to amines
title_short Simple electrochemical reduction of nitrones to amines
title_sort simple electrochemical reduction of nitrones to amines
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6375361/
https://www.ncbi.nlm.nih.gov/pubmed/30842861
http://dx.doi.org/10.1039/c8sc04337j
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