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Efficiency of 3D‐Ordered Macroporous La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) as an Electrocatalyst for Aprotic Li‐O(2) Batteries
Li‐O(2) batteries (LOBs) with an extremely high theoretical energy density have been reported to be the most promising candidates for future electric storage systems. Porous catalysts can be beneficial for LOBs. Herein, 3D‐ordered macroporous La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) perovskite oxides (3D‐LS...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6376210/ https://www.ncbi.nlm.nih.gov/pubmed/30815329 http://dx.doi.org/10.1002/open.201800247 |
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author | Cheng, Junfang Jiang, Yuexing Zou, Lu Zhang, Ming Zhang, Guozhu Wang, Ziling Huang, Yizhen Chi, Bo Pu, Jian Jian, Li |
author_facet | Cheng, Junfang Jiang, Yuexing Zou, Lu Zhang, Ming Zhang, Guozhu Wang, Ziling Huang, Yizhen Chi, Bo Pu, Jian Jian, Li |
author_sort | Cheng, Junfang |
collection | PubMed |
description | Li‐O(2) batteries (LOBs) with an extremely high theoretical energy density have been reported to be the most promising candidates for future electric storage systems. Porous catalysts can be beneficial for LOBs. Herein, 3D‐ordered macroporous La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) perovskite oxides (3D‐LSCF) are applied as cathode catalysts in LOBs. With a high Brunauer‐Emmett‐Teller surface area (21.8 m(2) g(−1)) and unique honeycomb‐like macroporous structure, the 3D‐LSCF catalysts possess a much higher efficiency than La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) (LSCF) nanoparticles. The unique 3D‐ordered macropores play a significant role in the product deposition as well as oxygen and electrolyte transmission, which are crucial for the discharge‐charge processes of LOBs. |
format | Online Article Text |
id | pubmed-6376210 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-63762102019-02-27 Efficiency of 3D‐Ordered Macroporous La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) as an Electrocatalyst for Aprotic Li‐O(2) Batteries Cheng, Junfang Jiang, Yuexing Zou, Lu Zhang, Ming Zhang, Guozhu Wang, Ziling Huang, Yizhen Chi, Bo Pu, Jian Jian, Li ChemistryOpen Communications Li‐O(2) batteries (LOBs) with an extremely high theoretical energy density have been reported to be the most promising candidates for future electric storage systems. Porous catalysts can be beneficial for LOBs. Herein, 3D‐ordered macroporous La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) perovskite oxides (3D‐LSCF) are applied as cathode catalysts in LOBs. With a high Brunauer‐Emmett‐Teller surface area (21.8 m(2) g(−1)) and unique honeycomb‐like macroporous structure, the 3D‐LSCF catalysts possess a much higher efficiency than La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) (LSCF) nanoparticles. The unique 3D‐ordered macropores play a significant role in the product deposition as well as oxygen and electrolyte transmission, which are crucial for the discharge‐charge processes of LOBs. John Wiley and Sons Inc. 2019-02-14 /pmc/articles/PMC6376210/ /pubmed/30815329 http://dx.doi.org/10.1002/open.201800247 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
spellingShingle | Communications Cheng, Junfang Jiang, Yuexing Zou, Lu Zhang, Ming Zhang, Guozhu Wang, Ziling Huang, Yizhen Chi, Bo Pu, Jian Jian, Li Efficiency of 3D‐Ordered Macroporous La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) as an Electrocatalyst for Aprotic Li‐O(2) Batteries |
title | Efficiency of 3D‐Ordered Macroporous La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) as an Electrocatalyst for Aprotic Li‐O(2) Batteries |
title_full | Efficiency of 3D‐Ordered Macroporous La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) as an Electrocatalyst for Aprotic Li‐O(2) Batteries |
title_fullStr | Efficiency of 3D‐Ordered Macroporous La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) as an Electrocatalyst for Aprotic Li‐O(2) Batteries |
title_full_unstemmed | Efficiency of 3D‐Ordered Macroporous La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) as an Electrocatalyst for Aprotic Li‐O(2) Batteries |
title_short | Efficiency of 3D‐Ordered Macroporous La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) as an Electrocatalyst for Aprotic Li‐O(2) Batteries |
title_sort | efficiency of 3d‐ordered macroporous la(0.6)sr(0.4)co(0.2)fe(0.8)o(3) as an electrocatalyst for aprotic li‐o(2) batteries |
topic | Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6376210/ https://www.ncbi.nlm.nih.gov/pubmed/30815329 http://dx.doi.org/10.1002/open.201800247 |
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