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Copper oxide–graphene oxide nanocomposite: efficient catalyst for hydrogenation of nitroaromatics in water

A low-cost nanocomposite catalyst containing copper oxide (CuO) nanoparticles (NPs) on graphene oxide (GO) was fabricated by a facile hydrothermal self-assembly process. The segregated CuO NPs and GO exhibited negligible catalytic activities for the reduction of nitroaromatics. However, their hybrid...

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Detalles Bibliográficos
Autores principales: Zhang, Kaiqiang, Suh, Jun Min, Lee, Tae Hyung, Cha, Joo Hwan, Choi, Ji-Won, Jang, Ho Won, Varma, Rajender S., Shokouhimehr, Mohammadreza
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Singapore 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6382917/
https://www.ncbi.nlm.nih.gov/pubmed/30788636
http://dx.doi.org/10.1186/s40580-019-0176-3
Descripción
Sumario:A low-cost nanocomposite catalyst containing copper oxide (CuO) nanoparticles (NPs) on graphene oxide (GO) was fabricated by a facile hydrothermal self-assembly process. The segregated CuO NPs and GO exhibited negligible catalytic activities for the reduction of nitroaromatics. However, their hybrid composite accomplished facile reduction with high conversions for several substituted nitroaromatics in aqueous NaBH(4) solution; synergetic coupling effect of CuO NPs with GO in the nanocomposite catalyst provided excellent catalytic activity. The nanocomposite catalyst could be separated from the reaction mixture and recycled consecutively.