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Total synthesis of micrococcin P1 and thiocillin I enabled by Mo(vi) catalyst

Thiopeptides are a class of potent antibiotics with promising therapeutic potential. We developed a novel Mo(vi)-oxide/picolinic acid catalyst for the cyclodehydration of cysteine peptides to form thiazoline heterocycles. With this powerful tool in hand, we completed the total syntheses of two repre...

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Detalles Bibliográficos
Autores principales:	Akasapu, Siddhartha, Hinds, Aaron B., Powell, Wyatt C., Walczak, Maciej A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6383332/ https://www.ncbi.nlm.nih.gov/pubmed/30881626 http://dx.doi.org/10.1039/c8sc04885a

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