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Selective C-N σ Bond Cleavage in Azetidinyl Amides under Transition Metal-Free Conditions
Functionalization of amide bond via the cleavage of a non-carbonyl, C-N σ bond remains under-investigated. In this work, a transition-metal-free single-electron transfer reaction has been developed for the C-N σ bond cleavage of N-acylazetidines using the electride derived from sodium dispersions an...
Autores principales: | Li, Hengzhao, Lai, Zemin, Adijiang, Adila, Zhao, Hongye, An, Jie |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6384560/ https://www.ncbi.nlm.nih.gov/pubmed/30696043 http://dx.doi.org/10.3390/molecules24030459 |
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