HMPA-Catalyzed Transfer Hydrogenation of 3-Carbonyl Pyridines and Other N-Heteroarenes with Trichlorosilane

A method for the HMPA (hexamethylphosphoric triamide)-catalyzed metal-free transfer hydrogenation of pyridines has been developed. The functional group tolerance of the existing reaction conditions provides easy access to various piperidines with ester or ketone groups at the C-3 site. The suitabili...

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Detalles Bibliográficos
Autores principales: Fu, Yun, Sun, Jian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6384841/
https://www.ncbi.nlm.nih.gov/pubmed/30678314
http://dx.doi.org/10.3390/molecules24030401

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6384841/
https://www.ncbi.nlm.nih.gov/pubmed/30678314
http://dx.doi.org/10.3390/molecules24030401

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