Synthesis, Characterization, Absorption Properties, and Electronic Structures of Paddlewheel-Type Dirhodium(II) Tetra-μ-(n-naphthoate) Complexes: An Experimental and Theoretical Study

The reactions of [Rh(2)(O(2)CCH(3))(4)(OH(2))(2)] with n-naphthalenecarboxylic acids (n = 1: 1-HNC, n = 2: 2-HNC) afford the dirhodium tetra-μ-(n-naphthoate) complexes [Rh(2)(1-NC)(4)] (1) and [Rh(2)(2-NC)(4)] (2), respectively. Single crystal X-ray diffraction analyses of [1(OCMe(2))(2)] and [2(OCM...

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Detalles Bibliográficos
Autores principales: Kataoka, Yusuke, Fukumoto, Raiki, Yano, Natsumi, Atarashi, Daiki, Tanaka, Hidekazu, Kawamoto, Tatsuya, Handa, Makoto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6384905/
https://www.ncbi.nlm.nih.gov/pubmed/30691216
http://dx.doi.org/10.3390/molecules24030447

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