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Mannich Base as Corrosion Inhibitors for N80 Steel in a CO(2) Saturated Solution Containing 3 wt % NaCl
In this paper, a corrosion inhibitor containing nitrogen atoms and a conjugated π bond was synthesised, and its final product synthesised by the optimal conditions of the orthogonal test results is named multi-mannich base (MBT). The corrosion inhibition effect on the N80 steel sheet of the corrosio...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6384954/ https://www.ncbi.nlm.nih.gov/pubmed/30717150 http://dx.doi.org/10.3390/ma12030449 |
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author | Tang, Mingjin Li, Jianbo Li, Zhida Fu, Luoping Zeng, Bo Lv, Jie |
author_facet | Tang, Mingjin Li, Jianbo Li, Zhida Fu, Luoping Zeng, Bo Lv, Jie |
author_sort | Tang, Mingjin |
collection | PubMed |
description | In this paper, a corrosion inhibitor containing nitrogen atoms and a conjugated π bond was synthesised, and its final product synthesised by the optimal conditions of the orthogonal test results is named multi-mannich base (MBT). The corrosion inhibition effect on the N80 steel sheet of the corrosion inhibitor was evaluated in a CO(2) saturated solution containing 3 wt % NaCl; the corrosion rate was 0.0446 mm/a and the corrosion inhibition rate was 90.4%. Through electrochemical and adsorption theory study, MBT is a mixed corrosion inhibitor that mainly shows cathode suppression capacity. The adsorption of MBT on the surface of the steel sheet follows the Langmuir adsorption isotherm; it can be spontaneously adsorbed on the surface of the N80 steel sheet, which has a good corrosion inhibition effect. The surface of the N80 steel sheet was microscopically characterised by atomic force microscope (AFM). It can be seen from the results that the N80 steel sheet with MBT added is significantly different from the blank control group; the surface of the steel sheet is relatively smooth, indicating that MBT forms an effective protective film on the surface of N80 steel, which inhibits the steel sheet. |
format | Online Article Text |
id | pubmed-6384954 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-63849542019-02-23 Mannich Base as Corrosion Inhibitors for N80 Steel in a CO(2) Saturated Solution Containing 3 wt % NaCl Tang, Mingjin Li, Jianbo Li, Zhida Fu, Luoping Zeng, Bo Lv, Jie Materials (Basel) Article In this paper, a corrosion inhibitor containing nitrogen atoms and a conjugated π bond was synthesised, and its final product synthesised by the optimal conditions of the orthogonal test results is named multi-mannich base (MBT). The corrosion inhibition effect on the N80 steel sheet of the corrosion inhibitor was evaluated in a CO(2) saturated solution containing 3 wt % NaCl; the corrosion rate was 0.0446 mm/a and the corrosion inhibition rate was 90.4%. Through electrochemical and adsorption theory study, MBT is a mixed corrosion inhibitor that mainly shows cathode suppression capacity. The adsorption of MBT on the surface of the steel sheet follows the Langmuir adsorption isotherm; it can be spontaneously adsorbed on the surface of the N80 steel sheet, which has a good corrosion inhibition effect. The surface of the N80 steel sheet was microscopically characterised by atomic force microscope (AFM). It can be seen from the results that the N80 steel sheet with MBT added is significantly different from the blank control group; the surface of the steel sheet is relatively smooth, indicating that MBT forms an effective protective film on the surface of N80 steel, which inhibits the steel sheet. MDPI 2019-02-01 /pmc/articles/PMC6384954/ /pubmed/30717150 http://dx.doi.org/10.3390/ma12030449 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Tang, Mingjin Li, Jianbo Li, Zhida Fu, Luoping Zeng, Bo Lv, Jie Mannich Base as Corrosion Inhibitors for N80 Steel in a CO(2) Saturated Solution Containing 3 wt % NaCl |
title | Mannich Base as Corrosion Inhibitors for N80 Steel in a CO(2) Saturated Solution Containing 3 wt % NaCl |
title_full | Mannich Base as Corrosion Inhibitors for N80 Steel in a CO(2) Saturated Solution Containing 3 wt % NaCl |
title_fullStr | Mannich Base as Corrosion Inhibitors for N80 Steel in a CO(2) Saturated Solution Containing 3 wt % NaCl |
title_full_unstemmed | Mannich Base as Corrosion Inhibitors for N80 Steel in a CO(2) Saturated Solution Containing 3 wt % NaCl |
title_short | Mannich Base as Corrosion Inhibitors for N80 Steel in a CO(2) Saturated Solution Containing 3 wt % NaCl |
title_sort | mannich base as corrosion inhibitors for n80 steel in a co(2) saturated solution containing 3 wt % nacl |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6384954/ https://www.ncbi.nlm.nih.gov/pubmed/30717150 http://dx.doi.org/10.3390/ma12030449 |
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