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Ti-V-C-Based Alloy with a FCC Lattice Structure for Hydrogen Storage

Here we report a Ti(50)V(50)-10 wt.% C alloy with a unique lattice and microstructure for hydrogen storage development. Different from a traditionally synthesized Ti(50)V(50) alloy prepared by a melting method and having a body-centered cubic (BCC) structure, this Ti(50)V(50)-C alloy synthesized by...

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Autores principales: Li, Bo, He, Liqing, Li, Jianding, Li, Hai-Wen, Lu, Zhouguang, Shao, Huaiyu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6384978/
https://www.ncbi.nlm.nih.gov/pubmed/30717403
http://dx.doi.org/10.3390/molecules24030552
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author Li, Bo
He, Liqing
Li, Jianding
Li, Hai-Wen
Lu, Zhouguang
Shao, Huaiyu
author_facet Li, Bo
He, Liqing
Li, Jianding
Li, Hai-Wen
Lu, Zhouguang
Shao, Huaiyu
author_sort Li, Bo
collection PubMed
description Here we report a Ti(50)V(50)-10 wt.% C alloy with a unique lattice and microstructure for hydrogen storage development. Different from a traditionally synthesized Ti(50)V(50) alloy prepared by a melting method and having a body-centered cubic (BCC) structure, this Ti(50)V(50)-C alloy synthesized by a mechanical alloying method is with a face-centered cubic (FCC) structure (space group: Fm-3m No. 225). The crystalline size is 60 nm. This alloy may directly absorb hydrogen near room temperature without any activation process. Mechanisms of the good kinetics from lattice and microstructure aspects were discussed. Findings reported here may indicate a new possibility in the development of future hydrogen storage materials.
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spelling pubmed-63849782019-02-23 Ti-V-C-Based Alloy with a FCC Lattice Structure for Hydrogen Storage Li, Bo He, Liqing Li, Jianding Li, Hai-Wen Lu, Zhouguang Shao, Huaiyu Molecules Article Here we report a Ti(50)V(50)-10 wt.% C alloy with a unique lattice and microstructure for hydrogen storage development. Different from a traditionally synthesized Ti(50)V(50) alloy prepared by a melting method and having a body-centered cubic (BCC) structure, this Ti(50)V(50)-C alloy synthesized by a mechanical alloying method is with a face-centered cubic (FCC) structure (space group: Fm-3m No. 225). The crystalline size is 60 nm. This alloy may directly absorb hydrogen near room temperature without any activation process. Mechanisms of the good kinetics from lattice and microstructure aspects were discussed. Findings reported here may indicate a new possibility in the development of future hydrogen storage materials. MDPI 2019-02-02 /pmc/articles/PMC6384978/ /pubmed/30717403 http://dx.doi.org/10.3390/molecules24030552 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Li, Bo
He, Liqing
Li, Jianding
Li, Hai-Wen
Lu, Zhouguang
Shao, Huaiyu
Ti-V-C-Based Alloy with a FCC Lattice Structure for Hydrogen Storage
title Ti-V-C-Based Alloy with a FCC Lattice Structure for Hydrogen Storage
title_full Ti-V-C-Based Alloy with a FCC Lattice Structure for Hydrogen Storage
title_fullStr Ti-V-C-Based Alloy with a FCC Lattice Structure for Hydrogen Storage
title_full_unstemmed Ti-V-C-Based Alloy with a FCC Lattice Structure for Hydrogen Storage
title_short Ti-V-C-Based Alloy with a FCC Lattice Structure for Hydrogen Storage
title_sort ti-v-c-based alloy with a fcc lattice structure for hydrogen storage
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6384978/
https://www.ncbi.nlm.nih.gov/pubmed/30717403
http://dx.doi.org/10.3390/molecules24030552
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