MoS(2)-Catalyzed transamidation reaction

The MoS(2)-catalyzed transamidation reaction with high yields using N,N-dimethylformamide and other amides as carbonyl sources is developed here. The protocol is simple, does not require any additive such as acid, base, ligand, etc., and encompasses a broad substrate scope for primary, secondary and...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Feng, Li, Lesong, Ma, Juan, Gong, Hang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385372/
https://www.ncbi.nlm.nih.gov/pubmed/30796297
http://dx.doi.org/10.1038/s41598-019-39210-5
Descripción
Sumario:The MoS(2)-catalyzed transamidation reaction with high yields using N,N-dimethylformamide and other amides as carbonyl sources is developed here. The protocol is simple, does not require any additive such as acid, base, ligand, etc., and encompasses a broad substrate scope for primary, secondary and heterocyclic amines. Moreover, the acetylation and propanylation of amines also can be achieved with good to excellent yield by this strategy.

Ejemplares similares