MoS(2)-Catalyzed transamidation reaction

The MoS(2)-catalyzed transamidation reaction with high yields using N,N-dimethylformamide and other amides as carbonyl sources is developed here. The protocol is simple, does not require any additive such as acid, base, ligand, etc., and encompasses a broad substrate scope for primary, secondary and...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Feng, Li, Lesong, Ma, Juan, Gong, Hang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385372/
https://www.ncbi.nlm.nih.gov/pubmed/30796297
http://dx.doi.org/10.1038/s41598-019-39210-5
_version_ 1783397188627333120
author Zhang, Feng
Li, Lesong
Ma, Juan
Gong, Hang
author_facet Zhang, Feng
Li, Lesong
Ma, Juan
Gong, Hang
author_sort Zhang, Feng
collection PubMed
description The MoS(2)-catalyzed transamidation reaction with high yields using N,N-dimethylformamide and other amides as carbonyl sources is developed here. The protocol is simple, does not require any additive such as acid, base, ligand, etc., and encompasses a broad substrate scope for primary, secondary and heterocyclic amines. Moreover, the acetylation and propanylation of amines also can be achieved with good to excellent yield by this strategy.
format Online
Article
Text
id pubmed-6385372
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher Nature Publishing Group UK
record_format MEDLINE/PubMed
spelling pubmed-63853722019-02-27 MoS(2)-Catalyzed transamidation reaction Zhang, Feng Li, Lesong Ma, Juan Gong, Hang Sci Rep Article The MoS(2)-catalyzed transamidation reaction with high yields using N,N-dimethylformamide and other amides as carbonyl sources is developed here. The protocol is simple, does not require any additive such as acid, base, ligand, etc., and encompasses a broad substrate scope for primary, secondary and heterocyclic amines. Moreover, the acetylation and propanylation of amines also can be achieved with good to excellent yield by this strategy. Nature Publishing Group UK 2019-02-22 /pmc/articles/PMC6385372/ /pubmed/30796297 http://dx.doi.org/10.1038/s41598-019-39210-5 Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Zhang, Feng
Li, Lesong
Ma, Juan
Gong, Hang
MoS(2)-Catalyzed transamidation reaction
title MoS(2)-Catalyzed transamidation reaction
title_full MoS(2)-Catalyzed transamidation reaction
title_fullStr MoS(2)-Catalyzed transamidation reaction
title_full_unstemmed MoS(2)-Catalyzed transamidation reaction
title_short MoS(2)-Catalyzed transamidation reaction
title_sort mos(2)-catalyzed transamidation reaction
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385372/
https://www.ncbi.nlm.nih.gov/pubmed/30796297
http://dx.doi.org/10.1038/s41598-019-39210-5
work_keys_str_mv AT zhangfeng mos2catalyzedtransamidationreaction
AT lilesong mos2catalyzedtransamidationreaction
AT majuan mos2catalyzedtransamidationreaction
AT gonghang mos2catalyzedtransamidationreaction

Ejemplares similares