A hypervalent and cubically coordinated molecular phase of IF(8) predicted at high pressure

Up to now, the maximum coordination number of iodine is seven in neutral iodine heptafluoride (IF(7)) and eight in anionic octafluoride (IF(8)(–)). Here, we explore pressure as a method for realizing new hypercoordinated iodine compounds. First-principles swarm structure calculations have been used...

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Detalles Bibliográficos
Autores principales: Luo, Dongbao, Lv, Jian, Peng, Feng, Wang, Yanchao, Yang, Guochun, Rahm, Martin, Ma, Yanming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385887/
https://www.ncbi.nlm.nih.gov/pubmed/30881685
http://dx.doi.org/10.1039/c8sc04635b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385887/
https://www.ncbi.nlm.nih.gov/pubmed/30881685
http://dx.doi.org/10.1039/c8sc04635b

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