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Reversible alkene binding and allylic C–H activation with an aluminium(i) complex

The monomeric molecular aluminium(i) complex 1 [{(ArNCMe)(2)CH}Al] (Ar = 2,6-di-iso-propylphenyl) reacts with a series of terminal and strained alkenes including ethylene, propylene, allylbenzene and norbornene to form alkene bound products. Remarkably all these reactions are reversible under mild c...

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Detalles Bibliográficos
Autores principales:	Bakewell, Clare, White, Andrew J. P., Crimmin, Mark R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6388093/ https://www.ncbi.nlm.nih.gov/pubmed/30881673 http://dx.doi.org/10.1039/c8sc04865g

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