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Carbon nitride photocatalyzes regioselective aminium radical addition to the carbonyl bond and yields N-fused pyrroles

Addition of N-centered radicals to C=C bonds or insertion into C–H bonds is well represented in the literature. These reactions have a tremendous significance, because they afford polyfunctionalized organic molecules. Despite the tetrahydroisoquinoline (THIQ) moiety widely occurring in natural biolo...

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Detalles Bibliográficos
Autores principales: Kurpil, Bogdan, Otte, Katharina, Mishchenko, Artem, Lamagni, Paolo, Lipiński, Wojciech, Lock, Nina, Antonietti, Markus, Savateev, Aleksandr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6391478/
https://www.ncbi.nlm.nih.gov/pubmed/30808862
http://dx.doi.org/10.1038/s41467-019-08652-w