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A Tautoleptic Approach to Chiral Hydrogen‐Bonded Supramolecular Tubular Polymers with Large Cavity

A new strategy towards tubular hydrogen‐bonded polymers based on the self‐assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by (1)H fast magic‐angle spinning (MAS) solid‐state NMR. The molecular tubes obtained possess large internal diamete...

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Autores principales: Neniškis, Algirdas, Račkauskaitė, Dovilė, Shi, Qixun, Robertson, Aiden J., Marsh, Andrew, Ulčinas, Artūras, Valiokas, Ramūnas, Brown, Steven P., Wärnmark, Kenneth, Orentas, Edvinas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6391958/
https://www.ncbi.nlm.nih.gov/pubmed/30070741
http://dx.doi.org/10.1002/chem.201803701
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author Neniškis, Algirdas
Račkauskaitė, Dovilė
Shi, Qixun
Robertson, Aiden J.
Marsh, Andrew
Ulčinas, Artūras
Valiokas, Ramūnas
Brown, Steven P.
Wärnmark, Kenneth
Orentas, Edvinas
author_facet Neniškis, Algirdas
Račkauskaitė, Dovilė
Shi, Qixun
Robertson, Aiden J.
Marsh, Andrew
Ulčinas, Artūras
Valiokas, Ramūnas
Brown, Steven P.
Wärnmark, Kenneth
Orentas, Edvinas
author_sort Neniškis, Algirdas
collection PubMed
description A new strategy towards tubular hydrogen‐bonded polymers based on the self‐assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by (1)H fast magic‐angle spinning (MAS) solid‐state NMR. The molecular tubes obtained possess large internal diameter and tailor‐made outer functionalities rendering them potential candidates for a number of applications.
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spelling pubmed-63919582019-03-07 A Tautoleptic Approach to Chiral Hydrogen‐Bonded Supramolecular Tubular Polymers with Large Cavity Neniškis, Algirdas Račkauskaitė, Dovilė Shi, Qixun Robertson, Aiden J. Marsh, Andrew Ulčinas, Artūras Valiokas, Ramūnas Brown, Steven P. Wärnmark, Kenneth Orentas, Edvinas Chemistry Communications A new strategy towards tubular hydrogen‐bonded polymers based on the self‐assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by (1)H fast magic‐angle spinning (MAS) solid‐state NMR. The molecular tubes obtained possess large internal diameter and tailor‐made outer functionalities rendering them potential candidates for a number of applications. John Wiley and Sons Inc. 2018-09-06 2018-09-20 /pmc/articles/PMC6391958/ /pubmed/30070741 http://dx.doi.org/10.1002/chem.201803701 Text en © 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Neniškis, Algirdas
Račkauskaitė, Dovilė
Shi, Qixun
Robertson, Aiden J.
Marsh, Andrew
Ulčinas, Artūras
Valiokas, Ramūnas
Brown, Steven P.
Wärnmark, Kenneth
Orentas, Edvinas
A Tautoleptic Approach to Chiral Hydrogen‐Bonded Supramolecular Tubular Polymers with Large Cavity
title A Tautoleptic Approach to Chiral Hydrogen‐Bonded Supramolecular Tubular Polymers with Large Cavity
title_full A Tautoleptic Approach to Chiral Hydrogen‐Bonded Supramolecular Tubular Polymers with Large Cavity
title_fullStr A Tautoleptic Approach to Chiral Hydrogen‐Bonded Supramolecular Tubular Polymers with Large Cavity
title_full_unstemmed A Tautoleptic Approach to Chiral Hydrogen‐Bonded Supramolecular Tubular Polymers with Large Cavity
title_short A Tautoleptic Approach to Chiral Hydrogen‐Bonded Supramolecular Tubular Polymers with Large Cavity
title_sort tautoleptic approach to chiral hydrogen‐bonded supramolecular tubular polymers with large cavity
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6391958/
https://www.ncbi.nlm.nih.gov/pubmed/30070741
http://dx.doi.org/10.1002/chem.201803701
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