Iridium‐Catalyzed α‐Selective Arylation of Styrenes by Dual C−H Functionalization

An Ir(I)‐system modified with a ferrocene derived bisphosphine ligand promotes α‐selective arylation of styrenes by dual C−H functionalization. These studies offer a regioisomeric alternative to the Pd‐catalyzed Fujiwara–Moritani reaction.

Detalles Bibliográficos
Autores principales: Cooper, Phillippa, Crisenza, Giacomo E. M., Feron, Lyman J., Bower, John F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6391973/
https://www.ncbi.nlm.nih.gov/pubmed/30171652
http://dx.doi.org/10.1002/anie.201808299
Descripción
Sumario:An Ir(I)‐system modified with a ferrocene derived bisphosphine ligand promotes α‐selective arylation of styrenes by dual C−H functionalization. These studies offer a regioisomeric alternative to the Pd‐catalyzed Fujiwara–Moritani reaction.

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