Cargando…

Enantioselective Rhodium-Catalyzed Cycloisomerization of 1,6-Allenynes to access 5/6-Fused Bicycle[4.3.0]nonadienes

Transition-metal-catalyzed cycloisomerization of 1,n-allenynes represents a powerful synthetic tool to rapidly assemble complex polycyclic skeletons from simple linear substrates. Nevertheless, there are no reports of the asymmetric version of these reactions. Moreover, most of these reactions proce...

Descripción completa

Detalles Bibliográficos
Autores principales:	Deng, Xu, Shi, Li-Yang, Lan, Jialing, Guan, Yu-Qing, Zhang, Xiaoyong, Lv, Hui, Chung, Lung Wa, Zhang, Xumu
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2019
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6393573/ https://www.ncbi.nlm.nih.gov/pubmed/30814517 http://dx.doi.org/10.1038/s41467-019-08900-z

Ejemplares similares

Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
por: You, Cai, et al.
Publicado: (2018)

A rhodium catalyzed cycloisomerization and tandem Diels–Alder reaction for facile access to diverse bicyclic and tricyclic heterocycles
por: Zhou, Yirong, et al.
Publicado: (2019)

Palladium-Catalyzed Oxidative Acyloxylation/Carbocyclization of Allenynes**
por: Deng, Youqian, et al.
Publicado: (2013)

Control of Selectivity in Palladium-Catalyzed Oxidative Carbocyclization/Borylation of Allenynes**
por: Deng, Youqian, et al.
Publicado: (2013)

Gold-Catalyzed Enantioselective Ring-Expanding Cycloisomerization of Cyclopropylidene Bearing 1,5-Enynes
por: Zheng, Hongchao, et al.
Publicado: (2014)

Electrooxidative palladium- and enantioselective rhodium-catalyzed [3 + 2] spiroannulations
por: Wei, Wen, et al.
Publicado: (2022)

Rhodium-catalyzed enantioselective and diastereodivergent access to diaxially chiral heterocycles
por: Wang, Yishou, et al.
Publicado: (2023)

Rhodium-catalyzed asymmetric hydrogenation of β-cyanocinnamic esters with the assistance of a single hydrogen bond in a precise position
por: Li, Xiuxiu, et al.
Publicado: (2018)

Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes
por: Smith, James R., et al.
Publicado: (2017)

Ring-fused cyclobutanes via cycloisomerization of alkylidenecyclopropane acylsilanes
por: Eichenberger, Sarah, et al.
Publicado: (2020)

Diastereoselective Pt Catalyzed Cycloisomerization of Polyenes to Polycycles
por: Geier, Michael J., et al.
Publicado: (2014)

Gold‐Catalyzed Cycloisomerization of Sulfur Ylides to Dihydrobenzothiepines
por: Knittl‐Frank, Christian, et al.
Publicado: (2020)

Mechanistic insights into rhodium-catalyzed enantioselective allylic alkylation for quaternary stereogenic centers
por: Pareek, Monika, et al.
Publicado: (2020)

Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes
por: Zhang, Dongquan, et al.
Publicado: (2021)

Regioselective access to polycyclic N-heterocycles via homogeneous copper-catalyzed cascade cyclization of allenynes
por: Wei, Kua-Fei, et al.
Publicado: (2023)

Asymmetric Au-catalyzed cycloisomerization of 1,6-enynes: An entry to bicyclo[4.1.0]heptene
por: Pradal, Alexandre, et al.
Publicado: (2011)

Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes
por: Cai, Zhong-Jian, et al.
Publicado: (2019)

Synthesis of Functionalized Azepines via Cu(I)-Catalyzed Tandem Amination/Cyclization Reaction of Fluorinated Allenynes
por: Philippova, Anna N., et al.
Publicado: (2022)

Synthesis of functionalized macrocyclic derivatives of trioxabicyclo[3.3.0]nonadiene
por: Leber, Sabine, et al.
Publicado: (2012)

Cobalt-catalyzed highly enantioselective hydrogenation of α,β-unsaturated carboxylic acids
por: Du, Xiaoyong, et al.
Publicado: (2020)

Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration
por: Callingham, Michael, et al.
Publicado: (2017)

Formal total synthesis of macarpine via a Au(I)-catalyzed 6-endo-dig cycloisomerization strategy
por: Fu, Jiayue, et al.
Publicado: (2022)

Enantioselective Synthesis of Spiroindenes by Enol-Directed Rhodium(III)-Catalyzed C–H Functionalization and Spiroannulation
por: Reddy Chidipudi, Suresh, et al.
Publicado: (2015)

Traceless Rhodium‐Catalyzed Hydroacylation Using Alkyl Aldehydes: The Enantioselective Synthesis of β‐Aryl Ketones
por: Bouisseau, Anaïs, et al.
Publicado: (2016)

Access to the Protoilludane Core by Gold-Catalyzed Allene-vinylcyclopropane Cycloisomerization
por: Pitaval, Anthony, et al.
Publicado: (2013)

Access to the Protoilludane Core by Gold-Catalyzed Allene-vinylcyclopropane Cycloisomerization
por: Pitaval, Anthony, et al.
Publicado: (2013)

Design and Synthesis of Pyrrolidinyl Ferrocene-Containing Ligands and Their Application in Highly Enantioselective Rhodium-Catalyzed Olefin Hydrogenation
por: Li, Xin, et al.
Publicado: (2022)

Enantioselective rhodium-catalyzed addition of arylboronic acids to N-heteroaryl ketones: synthesis of α-hydroxy acids
por: Zhu, Jinbin, et al.
Publicado: (2023)

Synthesis of a novel chemotype via sequential metal-catalyzed cycloisomerizations
por: Leng, Bo, et al.
Publicado: (2012)

Gold-Catalyzed Regioselective Synthesis of Crowded Cyclopentadienes by Migratory Cycloisomerization of Vinylallenes
por: Bernardo, Olaya, et al.
Publicado: (2022)

Sequencing palladium-catalyzed cycloisomerization cascades in a synthesis of the gelsemine core
por: Liang, Guoduan, et al.
Publicado: (2023)

Effective synthesis of bicyclodienes via palladium-catalyzed asymmetric allylic alkylation and ruthenium-catalyzed cycloisomerization
por: HAVARE, Nizam
Publicado: (2020)

Enantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes
por: Liu, Jiawang, et al.
Publicado: (2017)

Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization
por: Carreras, Javier, et al.
Publicado: (2016)

Palladium‐Catalyzed Tandem Cycloisomerization/Cross‐Coupling of Carbonyl‐ and Imine‐Tethered Alkylidenecyclopropanes
por: Verdugo, Felipe, et al.
Publicado: (2022)

Cellulose-Supported Heterogeneous Gold-Catalyzed Cycloisomerization Reactions of Alkynoic Acids and Allenynamides
por: Deiana, Luca, et al.
Publicado: (2023)

Phosphine-Catalyzed Enantioselective Intramolecular [3+2] Annulations To Generate Fused Ring Systems
por: Lee, Sarah Yunmi, et al.
Publicado: (2015)

Rhodium-catalyzed enantioselective C–H alkynylation of sulfoxides in diverse patterns: desymmetrization, kinetic resolution, and parallel kinetic resolution
por: Kong, Lingheng, et al.
Publicado: (2022)

A gold-catalyzed alkyne-diol cycloisomerization for the synthesis of oxygenated 5,5-spiroketals
por: Tlais, Sami F, et al.
Publicado: (2011)

Gold(i)-catalyzed cycloisomerization of vinylidenecyclopropane-enes via carbene or non-carbene processes
por: Li, De-Yao, et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_89ts4pamcqv1jeh1krf8iivoh6