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Enantioselective Rhodium-Catalyzed Cycloisomerization of 1,6-Allenynes to access 5/6-Fused Bicycle[4.3.0]nonadienes

Transition-metal-catalyzed cycloisomerization of 1,n-allenynes represents a powerful synthetic tool to rapidly assemble complex polycyclic skeletons from simple linear substrates. Nevertheless, there are no reports of the asymmetric version of these reactions. Moreover, most of these reactions proce...

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Detalles Bibliográficos
Autores principales:	Deng, Xu, Shi, Li-Yang, Lan, Jialing, Guan, Yu-Qing, Zhang, Xiaoyong, Lv, Hui, Chung, Lung Wa, Zhang, Xumu
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2019
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6393573/ https://www.ncbi.nlm.nih.gov/pubmed/30814517 http://dx.doi.org/10.1038/s41467-019-08900-z

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