Crystal structure of a new tripotassium hexa­nickel iron hexa­phosphate

A new potassium-nickel iron phosphate, K(3)Ni(6)Fe(PO(4))(6), has been synthesized by solid-state reaction and structurally characterized by single-crystal X-ray diffraction and qualitative energy dispersive X-ray spectroscopy (EDS) analysis. The structure is built up by [FeO(6)], [PO(4)], and [NiO(...

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Autores principales: Ouaatta, Said, Assani, Abderrazzak, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399685/
https://www.ncbi.nlm.nih.gov/pubmed/30867958
http://dx.doi.org/10.1107/S2056989019002706
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author Ouaatta, Said
Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
author_facet Ouaatta, Said
Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
author_sort Ouaatta, Said
collection PubMed
description A new potassium-nickel iron phosphate, K(3)Ni(6)Fe(PO(4))(6), has been synthesized by solid-state reaction and structurally characterized by single-crystal X-ray diffraction and qualitative energy dispersive X-ray spectroscopy (EDS) analysis. The structure is built up by [FeO(6)], [PO(4)], and [NiO(6)] coordination polyhedra, which are linked to each other by edge and corner sharing to form zigzag layers parallel to the ab plane. These layers are inter­connected by [PO(4)] tetra­hedra and [NiO(6)] octa­hedra via common corners, leading to a three-dimensional framework delimiting large channels running along the [100] direction in which the K(+) cations are localized.
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spelling pubmed-63996852019-03-13 Crystal structure of a new tripotassium hexa­nickel iron hexa­phosphate Ouaatta, Said Assani, Abderrazzak Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr E Crystallogr Commun Research Communications A new potassium-nickel iron phosphate, K(3)Ni(6)Fe(PO(4))(6), has been synthesized by solid-state reaction and structurally characterized by single-crystal X-ray diffraction and qualitative energy dispersive X-ray spectroscopy (EDS) analysis. The structure is built up by [FeO(6)], [PO(4)], and [NiO(6)] coordination polyhedra, which are linked to each other by edge and corner sharing to form zigzag layers parallel to the ab plane. These layers are inter­connected by [PO(4)] tetra­hedra and [NiO(6)] octa­hedra via common corners, leading to a three-dimensional framework delimiting large channels running along the [100] direction in which the K(+) cations are localized. International Union of Crystallography 2019-02-26 /pmc/articles/PMC6399685/ /pubmed/30867958 http://dx.doi.org/10.1107/S2056989019002706 Text en © Ouaatta et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Ouaatta, Said
Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
Crystal structure of a new tripotassium hexa­nickel iron hexa­phosphate
title Crystal structure of a new tripotassium hexa­nickel iron hexa­phosphate
title_full Crystal structure of a new tripotassium hexa­nickel iron hexa­phosphate
title_fullStr Crystal structure of a new tripotassium hexa­nickel iron hexa­phosphate
title_full_unstemmed Crystal structure of a new tripotassium hexa­nickel iron hexa­phosphate
title_short Crystal structure of a new tripotassium hexa­nickel iron hexa­phosphate
title_sort crystal structure of a new tripotassium hexa­nickel iron hexa­phosphate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399685/
https://www.ncbi.nlm.nih.gov/pubmed/30867958
http://dx.doi.org/10.1107/S2056989019002706
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AT saadimohamed crystalstructureofanewtripotassiumhexanickelironhexaphosphate
AT elammarilahcen crystalstructureofanewtripotassiumhexanickelironhexaphosphate

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