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Crystal structure of 3-meth­oxy-4-[2-(thia­zol-2-yl)diazen-1-yl]aniline monohydrate

In the title hydrated azo dye, C(10)H(10)N(4)OS·H(2)O, the benzene and thia­zole, are nearly coplanar, with a dihedral angle between their mean planes of 4.69 (17)°. The aromatic rings on the –N=N– moiety exhibit a trans configuration. The crystal structure features many types of inter­molecular int...

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Autores principales: Phiromphu, Nutchanikan, Chainok, Kittipong, Songsasen, Apisit, Duangthongyou, Tanwawan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399690/
https://www.ncbi.nlm.nih.gov/pubmed/30867948
http://dx.doi.org/10.1107/S205698901900207X
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author Phiromphu, Nutchanikan
Chainok, Kittipong
Songsasen, Apisit
Duangthongyou, Tanwawan
author_facet Phiromphu, Nutchanikan
Chainok, Kittipong
Songsasen, Apisit
Duangthongyou, Tanwawan
author_sort Phiromphu, Nutchanikan
collection PubMed
description In the title hydrated azo dye, C(10)H(10)N(4)OS·H(2)O, the benzene and thia­zole, are nearly coplanar, with a dihedral angle between their mean planes of 4.69 (17)°. The aromatic rings on the –N=N– moiety exhibit a trans configuration. The crystal structure features many types of inter­molecular inter­actions involving all the functional groups – strong hydrogen bonds (N⋯H and O⋯H), weak hydrogen bonds (C—H⋯O and C—H⋯N), C—H⋯π and π–π inter­actions – resulting in the formation of a three-dimensional framework.
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spelling pubmed-63996902019-03-13 Crystal structure of 3-meth­oxy-4-[2-(thia­zol-2-yl)diazen-1-yl]aniline monohydrate Phiromphu, Nutchanikan Chainok, Kittipong Songsasen, Apisit Duangthongyou, Tanwawan Acta Crystallogr E Crystallogr Commun Research Communications In the title hydrated azo dye, C(10)H(10)N(4)OS·H(2)O, the benzene and thia­zole, are nearly coplanar, with a dihedral angle between their mean planes of 4.69 (17)°. The aromatic rings on the –N=N– moiety exhibit a trans configuration. The crystal structure features many types of inter­molecular inter­actions involving all the functional groups – strong hydrogen bonds (N⋯H and O⋯H), weak hydrogen bonds (C—H⋯O and C—H⋯N), C—H⋯π and π–π inter­actions – resulting in the formation of a three-dimensional framework. International Union of Crystallography 2019-02-12 /pmc/articles/PMC6399690/ /pubmed/30867948 http://dx.doi.org/10.1107/S205698901900207X Text en © Phiromphu et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Phiromphu, Nutchanikan
Chainok, Kittipong
Songsasen, Apisit
Duangthongyou, Tanwawan
Crystal structure of 3-meth­oxy-4-[2-(thia­zol-2-yl)diazen-1-yl]aniline monohydrate
title Crystal structure of 3-meth­oxy-4-[2-(thia­zol-2-yl)diazen-1-yl]aniline monohydrate
title_full Crystal structure of 3-meth­oxy-4-[2-(thia­zol-2-yl)diazen-1-yl]aniline monohydrate
title_fullStr Crystal structure of 3-meth­oxy-4-[2-(thia­zol-2-yl)diazen-1-yl]aniline monohydrate
title_full_unstemmed Crystal structure of 3-meth­oxy-4-[2-(thia­zol-2-yl)diazen-1-yl]aniline monohydrate
title_short Crystal structure of 3-meth­oxy-4-[2-(thia­zol-2-yl)diazen-1-yl]aniline monohydrate
title_sort crystal structure of 3-meth­oxy-4-[2-(thia­zol-2-yl)diazen-1-yl]aniline monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399690/
https://www.ncbi.nlm.nih.gov/pubmed/30867948
http://dx.doi.org/10.1107/S205698901900207X
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