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Crystal structure of 3-methoxy-4-[2-(thiazol-2-yl)diazen-1-yl]aniline monohydrate
In the title hydrated azo dye, C(10)H(10)N(4)OS·H(2)O, the benzene and thiazole, are nearly coplanar, with a dihedral angle between their mean planes of 4.69 (17)°. The aromatic rings on the –N=N– moiety exhibit a trans configuration. The crystal structure features many types of intermolecular int...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399690/ https://www.ncbi.nlm.nih.gov/pubmed/30867948 http://dx.doi.org/10.1107/S205698901900207X |
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author | Phiromphu, Nutchanikan Chainok, Kittipong Songsasen, Apisit Duangthongyou, Tanwawan |
author_facet | Phiromphu, Nutchanikan Chainok, Kittipong Songsasen, Apisit Duangthongyou, Tanwawan |
author_sort | Phiromphu, Nutchanikan |
collection | PubMed |
description | In the title hydrated azo dye, C(10)H(10)N(4)OS·H(2)O, the benzene and thiazole, are nearly coplanar, with a dihedral angle between their mean planes of 4.69 (17)°. The aromatic rings on the –N=N– moiety exhibit a trans configuration. The crystal structure features many types of intermolecular interactions involving all the functional groups – strong hydrogen bonds (N⋯H and O⋯H), weak hydrogen bonds (C—H⋯O and C—H⋯N), C—H⋯π and π–π interactions – resulting in the formation of a three-dimensional framework. |
format | Online Article Text |
id | pubmed-6399690 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-63996902019-03-13 Crystal structure of 3-methoxy-4-[2-(thiazol-2-yl)diazen-1-yl]aniline monohydrate Phiromphu, Nutchanikan Chainok, Kittipong Songsasen, Apisit Duangthongyou, Tanwawan Acta Crystallogr E Crystallogr Commun Research Communications In the title hydrated azo dye, C(10)H(10)N(4)OS·H(2)O, the benzene and thiazole, are nearly coplanar, with a dihedral angle between their mean planes of 4.69 (17)°. The aromatic rings on the –N=N– moiety exhibit a trans configuration. The crystal structure features many types of intermolecular interactions involving all the functional groups – strong hydrogen bonds (N⋯H and O⋯H), weak hydrogen bonds (C—H⋯O and C—H⋯N), C—H⋯π and π–π interactions – resulting in the formation of a three-dimensional framework. International Union of Crystallography 2019-02-12 /pmc/articles/PMC6399690/ /pubmed/30867948 http://dx.doi.org/10.1107/S205698901900207X Text en © Phiromphu et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Phiromphu, Nutchanikan Chainok, Kittipong Songsasen, Apisit Duangthongyou, Tanwawan Crystal structure of 3-methoxy-4-[2-(thiazol-2-yl)diazen-1-yl]aniline monohydrate |
title | Crystal structure of 3-methoxy-4-[2-(thiazol-2-yl)diazen-1-yl]aniline monohydrate |
title_full | Crystal structure of 3-methoxy-4-[2-(thiazol-2-yl)diazen-1-yl]aniline monohydrate |
title_fullStr | Crystal structure of 3-methoxy-4-[2-(thiazol-2-yl)diazen-1-yl]aniline monohydrate |
title_full_unstemmed | Crystal structure of 3-methoxy-4-[2-(thiazol-2-yl)diazen-1-yl]aniline monohydrate |
title_short | Crystal structure of 3-methoxy-4-[2-(thiazol-2-yl)diazen-1-yl]aniline monohydrate |
title_sort | crystal structure of 3-methoxy-4-[2-(thiazol-2-yl)diazen-1-yl]aniline monohydrate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399690/ https://www.ncbi.nlm.nih.gov/pubmed/30867948 http://dx.doi.org/10.1107/S205698901900207X |
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