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Crystal structure of a 1:1 adduct of tri­phenyl­tin chloride with 3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one

In the centrosymmetric (racemic) title compound, chlorido­(3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one-κO)tri­phenyl­tin(IV), [Sn(C(6)H(5))(3)Cl(C(15)H(19)NOS)], the tin(IV) atom exhibits a trigonal–bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chl...

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Detalles Bibliográficos
Autores principales: Yennawar, Hemant P., Tierney, John, Cannon, Kevin C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399697/
https://www.ncbi.nlm.nih.gov/pubmed/30867944
http://dx.doi.org/10.1107/S2056989019001592
Descripción
Sumario:In the centrosymmetric (racemic) title compound, chlorido­(3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one-κO)tri­phenyl­tin(IV), [Sn(C(6)H(5))(3)Cl(C(15)H(19)NOS)], the tin(IV) atom exhibits a trigonal–bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chloride anion and ligand oxygen atom present at axial sites [O—Sn—Cl = 175.07 (14)°]. The thia­zolidinone ring of the ligand adopts an envelope conformation with the S atom as the flap. The dihedral angles between the heterocycle ring plane (all atoms) are 44.3 (9)° with respect to the pendant C-phenyl plane and 34.3 (11)° to the N-cyclo­hexyl ring (all atoms). The C-phenyl and N-cyclo­hexyl ring are close to orthogonal to each other, with a dihedral angle of 81.1 (4)° between them. In the crystal, mol­ecules are linked by weak C—H⋯Cl hydrogen bonds to generate [001] chains.