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Crystal structure of a 1:1 adduct of tri­phenyl­tin chloride with 3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one

In the centrosymmetric (racemic) title compound, chlorido­(3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one-κO)tri­phenyl­tin(IV), [Sn(C(6)H(5))(3)Cl(C(15)H(19)NOS)], the tin(IV) atom exhibits a trigonal–bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chl...

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Autores principales: Yennawar, Hemant P., Tierney, John, Cannon, Kevin C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399697/
https://www.ncbi.nlm.nih.gov/pubmed/30867944
http://dx.doi.org/10.1107/S2056989019001592
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author Yennawar, Hemant P.
Tierney, John
Cannon, Kevin C.
author_facet Yennawar, Hemant P.
Tierney, John
Cannon, Kevin C.
author_sort Yennawar, Hemant P.
collection PubMed
description In the centrosymmetric (racemic) title compound, chlorido­(3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one-κO)tri­phenyl­tin(IV), [Sn(C(6)H(5))(3)Cl(C(15)H(19)NOS)], the tin(IV) atom exhibits a trigonal–bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chloride anion and ligand oxygen atom present at axial sites [O—Sn—Cl = 175.07 (14)°]. The thia­zolidinone ring of the ligand adopts an envelope conformation with the S atom as the flap. The dihedral angles between the heterocycle ring plane (all atoms) are 44.3 (9)° with respect to the pendant C-phenyl plane and 34.3 (11)° to the N-cyclo­hexyl ring (all atoms). The C-phenyl and N-cyclo­hexyl ring are close to orthogonal to each other, with a dihedral angle of 81.1 (4)° between them. In the crystal, mol­ecules are linked by weak C—H⋯Cl hydrogen bonds to generate [001] chains.
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spelling pubmed-63996972019-03-13 Crystal structure of a 1:1 adduct of tri­phenyl­tin chloride with 3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one Yennawar, Hemant P. Tierney, John Cannon, Kevin C. Acta Crystallogr E Crystallogr Commun Research Communications In the centrosymmetric (racemic) title compound, chlorido­(3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one-κO)tri­phenyl­tin(IV), [Sn(C(6)H(5))(3)Cl(C(15)H(19)NOS)], the tin(IV) atom exhibits a trigonal–bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chloride anion and ligand oxygen atom present at axial sites [O—Sn—Cl = 175.07 (14)°]. The thia­zolidinone ring of the ligand adopts an envelope conformation with the S atom as the flap. The dihedral angles between the heterocycle ring plane (all atoms) are 44.3 (9)° with respect to the pendant C-phenyl plane and 34.3 (11)° to the N-cyclo­hexyl ring (all atoms). The C-phenyl and N-cyclo­hexyl ring are close to orthogonal to each other, with a dihedral angle of 81.1 (4)° between them. In the crystal, mol­ecules are linked by weak C—H⋯Cl hydrogen bonds to generate [001] chains. International Union of Crystallography 2019-02-08 /pmc/articles/PMC6399697/ /pubmed/30867944 http://dx.doi.org/10.1107/S2056989019001592 Text en © Yennawar et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Yennawar, Hemant P.
Tierney, John
Cannon, Kevin C.
Crystal structure of a 1:1 adduct of tri­phenyl­tin chloride with 3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one
title Crystal structure of a 1:1 adduct of tri­phenyl­tin chloride with 3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one
title_full Crystal structure of a 1:1 adduct of tri­phenyl­tin chloride with 3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one
title_fullStr Crystal structure of a 1:1 adduct of tri­phenyl­tin chloride with 3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one
title_full_unstemmed Crystal structure of a 1:1 adduct of tri­phenyl­tin chloride with 3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one
title_short Crystal structure of a 1:1 adduct of tri­phenyl­tin chloride with 3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one
title_sort crystal structure of a 1:1 adduct of tri­phenyl­tin chloride with 3-cyclo­hexhyl-2-phenyl-1,3-thia­zolidin-4-one
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399697/
https://www.ncbi.nlm.nih.gov/pubmed/30867944
http://dx.doi.org/10.1107/S2056989019001592
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