Cargando…
Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one
In the centrosymmetric (racemic) title compound, chlorido(3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one-κO)triphenyltin(IV), [Sn(C(6)H(5))(3)Cl(C(15)H(19)NOS)], the tin(IV) atom exhibits a trigonal–bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chl...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399697/ https://www.ncbi.nlm.nih.gov/pubmed/30867944 http://dx.doi.org/10.1107/S2056989019001592 |
_version_ | 1783399799935991808 |
---|---|
author | Yennawar, Hemant P. Tierney, John Cannon, Kevin C. |
author_facet | Yennawar, Hemant P. Tierney, John Cannon, Kevin C. |
author_sort | Yennawar, Hemant P. |
collection | PubMed |
description | In the centrosymmetric (racemic) title compound, chlorido(3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one-κO)triphenyltin(IV), [Sn(C(6)H(5))(3)Cl(C(15)H(19)NOS)], the tin(IV) atom exhibits a trigonal–bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chloride anion and ligand oxygen atom present at axial sites [O—Sn—Cl = 175.07 (14)°]. The thiazolidinone ring of the ligand adopts an envelope conformation with the S atom as the flap. The dihedral angles between the heterocycle ring plane (all atoms) are 44.3 (9)° with respect to the pendant C-phenyl plane and 34.3 (11)° to the N-cyclohexyl ring (all atoms). The C-phenyl and N-cyclohexyl ring are close to orthogonal to each other, with a dihedral angle of 81.1 (4)° between them. In the crystal, molecules are linked by weak C—H⋯Cl hydrogen bonds to generate [001] chains. |
format | Online Article Text |
id | pubmed-6399697 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-63996972019-03-13 Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one Yennawar, Hemant P. Tierney, John Cannon, Kevin C. Acta Crystallogr E Crystallogr Commun Research Communications In the centrosymmetric (racemic) title compound, chlorido(3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one-κO)triphenyltin(IV), [Sn(C(6)H(5))(3)Cl(C(15)H(19)NOS)], the tin(IV) atom exhibits a trigonal–bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chloride anion and ligand oxygen atom present at axial sites [O—Sn—Cl = 175.07 (14)°]. The thiazolidinone ring of the ligand adopts an envelope conformation with the S atom as the flap. The dihedral angles between the heterocycle ring plane (all atoms) are 44.3 (9)° with respect to the pendant C-phenyl plane and 34.3 (11)° to the N-cyclohexyl ring (all atoms). The C-phenyl and N-cyclohexyl ring are close to orthogonal to each other, with a dihedral angle of 81.1 (4)° between them. In the crystal, molecules are linked by weak C—H⋯Cl hydrogen bonds to generate [001] chains. International Union of Crystallography 2019-02-08 /pmc/articles/PMC6399697/ /pubmed/30867944 http://dx.doi.org/10.1107/S2056989019001592 Text en © Yennawar et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Yennawar, Hemant P. Tierney, John Cannon, Kevin C. Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one |
title | Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one |
title_full | Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one |
title_fullStr | Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one |
title_full_unstemmed | Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one |
title_short | Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one |
title_sort | crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399697/ https://www.ncbi.nlm.nih.gov/pubmed/30867944 http://dx.doi.org/10.1107/S2056989019001592 |
work_keys_str_mv | AT yennawarhemantp crystalstructureofa11adductoftriphenyltinchloridewith3cyclohexhyl2phenyl13thiazolidin4one AT tierneyjohn crystalstructureofa11adductoftriphenyltinchloridewith3cyclohexhyl2phenyl13thiazolidin4one AT cannonkevinc crystalstructureofa11adductoftriphenyltinchloridewith3cyclohexhyl2phenyl13thiazolidin4one |