Cargando…
A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate
Development of a bio-based wood adhesive is a significant goal for several wood-based material industries. In this study, a novel adhesive based upon sucrose and ammonium dihydrogen phosphate (ADP) was formulated in hopes of furthering this industrial goal through realization of a sustainable adhesi...
Autores principales: | , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6401688/ https://www.ncbi.nlm.nih.gov/pubmed/30961176 http://dx.doi.org/10.3390/polym10111251 |
_version_ | 1783400202105782272 |
---|---|
author | Zhao, Zhongyuan Hayashi, Shin Xu, Wei Wu, Zhihui Tanaka, Soichi Sun, Shijing Zhang, Min Kanayama, Kozo Umemura, Kenji |
author_facet | Zhao, Zhongyuan Hayashi, Shin Xu, Wei Wu, Zhihui Tanaka, Soichi Sun, Shijing Zhang, Min Kanayama, Kozo Umemura, Kenji |
author_sort | Zhao, Zhongyuan |
collection | PubMed |
description | Development of a bio-based wood adhesive is a significant goal for several wood-based material industries. In this study, a novel adhesive based upon sucrose and ammonium dihydrogen phosphate (ADP) was formulated in hopes of furthering this industrial goal through realization of a sustainable adhesive with mechanical properties and water resistance comparable to the synthetic resins used today. Finished particleboards exhibited excellent mechanical properties and water resistance at the revealed optimal adhesive conditions. In fact, the board properties fulfilled in principle the requirements of JIS A 5908 18 type standard, however this occured at production conditions for the actual state of development as reported here, which are still different to usual industrial conditions. Thermal analysis revealed addition of ADP resulted in decreases to the thermal thresholds associated with degradation and curing of sucrose. Spectral results of FT-IR elucidated that furanic ring chemistry was involved during adhesive curing. A possible polycondensation reaction pathway was proposed from this data in an attempt to explain why the adhesive exhibited such favorable bonding properties. |
format | Online Article Text |
id | pubmed-6401688 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-64016882019-04-02 A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate Zhao, Zhongyuan Hayashi, Shin Xu, Wei Wu, Zhihui Tanaka, Soichi Sun, Shijing Zhang, Min Kanayama, Kozo Umemura, Kenji Polymers (Basel) Article Development of a bio-based wood adhesive is a significant goal for several wood-based material industries. In this study, a novel adhesive based upon sucrose and ammonium dihydrogen phosphate (ADP) was formulated in hopes of furthering this industrial goal through realization of a sustainable adhesive with mechanical properties and water resistance comparable to the synthetic resins used today. Finished particleboards exhibited excellent mechanical properties and water resistance at the revealed optimal adhesive conditions. In fact, the board properties fulfilled in principle the requirements of JIS A 5908 18 type standard, however this occured at production conditions for the actual state of development as reported here, which are still different to usual industrial conditions. Thermal analysis revealed addition of ADP resulted in decreases to the thermal thresholds associated with degradation and curing of sucrose. Spectral results of FT-IR elucidated that furanic ring chemistry was involved during adhesive curing. A possible polycondensation reaction pathway was proposed from this data in an attempt to explain why the adhesive exhibited such favorable bonding properties. MDPI 2018-11-12 /pmc/articles/PMC6401688/ /pubmed/30961176 http://dx.doi.org/10.3390/polym10111251 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Zhao, Zhongyuan Hayashi, Shin Xu, Wei Wu, Zhihui Tanaka, Soichi Sun, Shijing Zhang, Min Kanayama, Kozo Umemura, Kenji A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate |
title | A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate |
title_full | A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate |
title_fullStr | A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate |
title_full_unstemmed | A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate |
title_short | A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate |
title_sort | novel eco-friendly wood adhesive composed by sucrose and ammonium dihydrogen phosphate |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6401688/ https://www.ncbi.nlm.nih.gov/pubmed/30961176 http://dx.doi.org/10.3390/polym10111251 |
work_keys_str_mv | AT zhaozhongyuan anovelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT hayashishin anovelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT xuwei anovelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT wuzhihui anovelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT tanakasoichi anovelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT sunshijing anovelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT zhangmin anovelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT kanayamakozo anovelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT umemurakenji anovelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT zhaozhongyuan novelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT hayashishin novelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT xuwei novelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT wuzhihui novelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT tanakasoichi novelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT sunshijing novelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT zhangmin novelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT kanayamakozo novelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate AT umemurakenji novelecofriendlywoodadhesivecomposedbysucroseandammoniumdihydrogenphosphate |