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A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate

Development of a bio-based wood adhesive is a significant goal for several wood-based material industries. In this study, a novel adhesive based upon sucrose and ammonium dihydrogen phosphate (ADP) was formulated in hopes of furthering this industrial goal through realization of a sustainable adhesi...

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Autores principales: Zhao, Zhongyuan, Hayashi, Shin, Xu, Wei, Wu, Zhihui, Tanaka, Soichi, Sun, Shijing, Zhang, Min, Kanayama, Kozo, Umemura, Kenji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6401688/
https://www.ncbi.nlm.nih.gov/pubmed/30961176
http://dx.doi.org/10.3390/polym10111251
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author Zhao, Zhongyuan
Hayashi, Shin
Xu, Wei
Wu, Zhihui
Tanaka, Soichi
Sun, Shijing
Zhang, Min
Kanayama, Kozo
Umemura, Kenji
author_facet Zhao, Zhongyuan
Hayashi, Shin
Xu, Wei
Wu, Zhihui
Tanaka, Soichi
Sun, Shijing
Zhang, Min
Kanayama, Kozo
Umemura, Kenji
author_sort Zhao, Zhongyuan
collection PubMed
description Development of a bio-based wood adhesive is a significant goal for several wood-based material industries. In this study, a novel adhesive based upon sucrose and ammonium dihydrogen phosphate (ADP) was formulated in hopes of furthering this industrial goal through realization of a sustainable adhesive with mechanical properties and water resistance comparable to the synthetic resins used today. Finished particleboards exhibited excellent mechanical properties and water resistance at the revealed optimal adhesive conditions. In fact, the board properties fulfilled in principle the requirements of JIS A 5908 18 type standard, however this occured at production conditions for the actual state of development as reported here, which are still different to usual industrial conditions. Thermal analysis revealed addition of ADP resulted in decreases to the thermal thresholds associated with degradation and curing of sucrose. Spectral results of FT-IR elucidated that furanic ring chemistry was involved during adhesive curing. A possible polycondensation reaction pathway was proposed from this data in an attempt to explain why the adhesive exhibited such favorable bonding properties.
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spelling pubmed-64016882019-04-02 A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate Zhao, Zhongyuan Hayashi, Shin Xu, Wei Wu, Zhihui Tanaka, Soichi Sun, Shijing Zhang, Min Kanayama, Kozo Umemura, Kenji Polymers (Basel) Article Development of a bio-based wood adhesive is a significant goal for several wood-based material industries. In this study, a novel adhesive based upon sucrose and ammonium dihydrogen phosphate (ADP) was formulated in hopes of furthering this industrial goal through realization of a sustainable adhesive with mechanical properties and water resistance comparable to the synthetic resins used today. Finished particleboards exhibited excellent mechanical properties and water resistance at the revealed optimal adhesive conditions. In fact, the board properties fulfilled in principle the requirements of JIS A 5908 18 type standard, however this occured at production conditions for the actual state of development as reported here, which are still different to usual industrial conditions. Thermal analysis revealed addition of ADP resulted in decreases to the thermal thresholds associated with degradation and curing of sucrose. Spectral results of FT-IR elucidated that furanic ring chemistry was involved during adhesive curing. A possible polycondensation reaction pathway was proposed from this data in an attempt to explain why the adhesive exhibited such favorable bonding properties. MDPI 2018-11-12 /pmc/articles/PMC6401688/ /pubmed/30961176 http://dx.doi.org/10.3390/polym10111251 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhao, Zhongyuan
Hayashi, Shin
Xu, Wei
Wu, Zhihui
Tanaka, Soichi
Sun, Shijing
Zhang, Min
Kanayama, Kozo
Umemura, Kenji
A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate
title A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate
title_full A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate
title_fullStr A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate
title_full_unstemmed A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate
title_short A Novel Eco-Friendly Wood Adhesive Composed by Sucrose and Ammonium Dihydrogen Phosphate
title_sort novel eco-friendly wood adhesive composed by sucrose and ammonium dihydrogen phosphate
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6401688/
https://www.ncbi.nlm.nih.gov/pubmed/30961176
http://dx.doi.org/10.3390/polym10111251
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