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Polymers of ε-Caprolactone Using New Copper(II) and Zinc(II) Complexes as Initiators: Synthesis, Characterization and X-Ray Crystal Structures

Five of six new Zn(II) and Cu(II) complexes were active in the ring-opening polymerization (ROP) of ε-caprolactone (CL) under solvent-free conditions, producing polycaprolactones (PCLs) of high crystallinity with molecular weights between 22,900 and 38,700 g mol(−1) and decomposition temperatures ab...

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Detalles Bibliográficos
Autores principales:	Posada, Andrés F., Macías, Mario A., Movilla, Santiago, Miscione, Gian Pietro, Pérez, León D., Hurtado, John J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2018
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6401771/ https://www.ncbi.nlm.nih.gov/pubmed/30961164 http://dx.doi.org/10.3390/polym10111239

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