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A Novel Ziegler–Natta-Type Catalytic System—TiCl(4)/2,2′-Dimethoxy-1,1′-Binaphthalene/Et(3)Al(2)Cl(3)/Bu(2)Mg for Production of Ultrahigh Molecular Weight Polyethylene Nascent Reactor Powders, Suitable for Solvent-Free Processing
A series of ultrahigh molecular weight polyethylenes with viscosity-average molecular weights in the range of 1.6–5.6 × 10(6) have been prepared by using a novel Ziegler–Natta-type catalytic system—TiCl(4)/2,2′-dimethoxy-1,1′-binaphthalene/Et(3)Al(2)Cl(3)/Bu(2)Mg at different temperatures (T(poly))...
Autores principales: | Serenko, Olga A., Buzin, Mikhail I., Tuskaev, Vladislav A., Gagieva, Svetlana C., Kolosov, Nikolay A., Kurmaev, Dmitrii A., Savel’eva, Tatyana F., Golubev, Evgenii K., Zubkevich, Sergey V., Vasil’ev, Viktor G., Nikiforova, Galina G., Korlyukov, Alexander A., Bulychev, Boris M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6401888/ https://www.ncbi.nlm.nih.gov/pubmed/30961206 http://dx.doi.org/10.3390/polym10111281 |
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